Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Yutaka Hitomi » Japanese

Affiliation Department of Applied Chemistry, Graduate School of Science and Engineering, Doshisha University
Position Professor
Contact Email
HP http://yutakahitomi.strikingly.com/
Speciality Bioinorganic Chemistry
Keyword Oxidation Reaction, Reactive Oxygen Species, Metal-oxo Species
Institute The Chemical Society of Japan, Japan Society of Coordination Chemistry, Catalyst Society of Japan, Society of Biological Inorganic Chemistry

Abstract

Development of Selective Oxidation Catalysts that Precisely Recognize Substrates in a Size-tunable Space

Achievement

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Original papers

  • "Green Fabrication of Nanoporous BiVO<sub>4</sub> Films on ITO Substrates for Photoelectrochemical Water-Oxidation"
    Okunaka, S.; Hitomi, Y.; *Tokudome, H.
    RSC Advances, 2018, 8, 31575
  • "Acceleration of Hydrolytic DNA Cleavage by Dicopper(II) Complexes with p-Cresol-Derived Dinucleating Ligands at Slightly Acidic pH and the Mechanistic Insights"
    *Kodera, M; Kadoya, Y.; Aso, K.; Fukui, K.;Nomura,A.; Hitomi, Y.; Kitagishi, H.
    Bull. Chem. Soc. Jpn, 2019, 92(4), 739
  • "Structurally Simple Cell-permeable Porphyrins: Efficient Cellular Uptake and Photo-toxicity of Porphyrins with Four Peripheral Primary-amine-terminated Oligo(ethylene oxide) Chains"
    Ohashi, N.; Nomura, A.; Kodera, M.; *Hitomi, Y.
    Chemistry Letters, 2017, 46(12), 1754-1756
  • "Specific Enhancement of Catalytic Activity by a Dicopper Core: Selective Hydroxylation of Benzene to Phenol with Hydrogen Peroxide"
    Tsuji, T.; Zaoputra, A. A.; Hitomi, Y.; Mieda, K.; Ogura, T.; Shiota, Y.; Yoshizawa, K.; Sato, H.; *Kodera, M.
    Angewandte Chemie International Edition, 2017,
  • "DNA Cleavage through Reductive Dioxygen Activation by Iron-Bleomycin Mimics with Carboxamido Ligation: Correlation between DNA Cleavage Efficacy and Redox Potential"
    Nomura, A.; Iwamoto, Y.; Arakawa, K.; Kashida, A.; Kodera, M.; *Hitomi, Y.
    Chemistry Letters, 2017,
  • "Formation and High Reactivity of the anti-Dioxo Form of High-Spin μ-Oxodioxodiiron(IV) as the Active Species That Cleaves Strong C−H Bonds"
    *Kodera, M.; Ishiga, S.; Tsuji, T.; Sakurai, K.; Hitomi, Y.; Shiota, Y.; Sajith, P. K.; Yoshizawa, K.; Mieda, K.; Ogura, T.
    Chem. Eur. J., 2016, 22(17), 5924-5936
  • "Preparation of Fine Particles of Sheelite-Monoclinic Phase BiVO4 via an Aqueous Chelating Method for Efficient Photocatalytic Oxygen Evolution under Visible-light Irradiation"
    Okunaka, S.; *Tokudome, H.; Hitomi, Y.; *Abe, R.
    J. Mater. Chem. A, 2016, 4, 3926-3932

Conference

  • 第4回精密制御反応場国際シンポジウム
    "Development of Artificial Nonheme Iron-dependent Peroxidase through Covalent Conjugation of Tetradentate Ligand with Protein", Poster Presentation
    Sugai, Y.; Ueno, K.; Kato, S.; Nomura, A.; Kodera, M.; Onoda, A.; Hayashi, T.; Hitomi, Y.
    12/3/2019~12/5/2019, Nara, Japan
  • 第4回精密制御反応場国際シンポジウム
    "Alkene Epoxidation with Electrochemically Generated Percarbonate Catalyzed by Manganese Complex", Poster Presentation
    Amanai, K.; ; Kodera, M.; Kitayama, K.; Hitomi, Y.
    12/3/2019~12/5/2019, Nara, Japan
  • 15th International Symposium on Applied Bioinorganic Chemistry
    "Synthesis and Reactivity of Ruthenium-Oxo Complexes Supported by Carboxylamido Ligands", Poster Presentation
    Wamura, S.; Kodera, M.; Kojima, T.; Hitomi, Y.
    6/2/2019~6/5/2019, Nara, Japan
  • 15th International Symposium on Applied Bioinorganic Chemistry
    "Selective Oxidation Catalyzed by Carboxylamidoiron(III) Complex with Restricted Reaction Space", Poster Presentation
    Adachi, H.; Kodera, M.; Hitomi, Y.
    6/2/2019~6/5/2019, Nara, Japan
  • 9th Asian Biological Inorganic Chemistry Conference
    "Detection and Generation of Hydrogen Peroxide by Functional Model Complexes", 招待講演
    Yutaka Hitomi
    12/9/2018~12/14/2018
  • The 25th International SPACC Symposium
    "Development of Oxidation Catalysts Based on Bio-inspired Iron Complexes", 口頭発表
    Yutaka Hitomi
    11/23/2018~11/25/2018
  • 43rd International Conference on Coordination Chemistry
    "Selective Alkane Oxidation Catalyzed by Mononuclear Nonheme Iron Complex", 招待講演
    Yutaka Hitomi
    7/30/2018~8/4/2018
  • International Congress on Pure & Applied Chemistry 2018
    "Development of Useful Molecules Based on Bioinspired Metal Complexes", Invited Lecture
    *HITOMI, Y.
    3/7/2018~3/10/2018, Siem Reap, Cambodia
  • EWHA Bioinorganic Chemistry Symposium 2017
    "Generation of Hydrogen Peroxide by Functional Model Complexes for Superoxide Dismutase", Invited Lecture
    *HITOMI, Y.
    12/1/2017~12/2/2017, Seoul, Korea
  • 2017 DGIST Global Innovation Festival
    "Site-Selective C-H Bond Oxidation Catalyzed by Mononuclear Nonheme Iron Complexes: Additive Effects of Carboxylic Acids", Invited Lecture
    *HITOMI, Y.
    11/29/2017~12/1/2017, Daegu, Korea
  • 8th Asian Biological Inorganic Chemistry Conference
    "Biologically Useful Functional Models of Metalloenzymes", Invited Lecture
    Hitomi, Y.
    12/4/2016~12/9/2016, Auckland, New Zealand
  • 1st Nano/Bioscience International Symposium
    "Synthetically and Biologically Useful Molecules Based on Bioinspired Complexes", Invited Lecture
    Hitomi, Y.
    10/7/2016~10/8/2016, Kyotanabe, Japan
  • 1st Japan-Australia Joint Symposium on Coordination Chemistry
    "Bioinspired Iron Catalysts for Selective Alkane Hydroxylation", Invited Lecture
    Hitomi, Y.
    9/8/2016~9/10/2016, Fukuoka, Japan
  • 42nd International Conference on Coordination Chemistry
    "Bioinspired Mononuclear Nonheme Iron Complexes for Detection of Hydrogen Peroxide inside Living Cells", Invited Lecture
    Hitomi, Y.
    7/3/2016~7/8/2016, Brest, France

National Conference

  • 日本化学会 第100春季年会 (2020)
    "カルボキサミドアニオン窒素配位を有する2-アミノフェノラート鉄錯体の反応性", 口頭発表
    長尾 鳳児郎・和村 聡士・小寺 政人・人見 穣
    3/22/2020~3/25/2020, 千葉
  • 日本化学会 第100春季年会 (2020)
    "イプチセン構造を有する錯体触媒の開発", 口頭発表
    福澤 哲生・足立 弘樹・小寺 政人・人見 穣
    3/22/2020~3/25/2020, 千葉
  • 日本化学会 第100春季年会 (2020)
    "活性酸素種を検出する新規蛍光プローブの開発", 口頭発表
    福井 悠介・上田 純平・小寺 政人・人見 穣
    3/22/2020~3/25/2020, 千葉
  • 日本化学会 第100春季年会 (2020)
    "キノリン骨格を有する新規レシオ型亜鉛蛍光プローブの開発", 口頭発表
    大橋 麻未・上田 純平・野村 章子・小寺 政人・人見 穣
    3/22/2020~3/25/2020, 千葉
  • 日本化学会 第100春季年会 (2020)
    "ニッケル錯体を触媒とするm-CPBAによるアルカン酸化反応", 口頭発表
    安野 里穂・上田 純平・小寺 政人・人見 穣
    3/22/2020~3/25/2020, 千葉
  • 第52回酸化反応討論会
    "タンパク質の反応空間を有する金属錯体酸化触媒の開発", ポスター発表
    菅井 優希、上野夏奈子、加藤俊介、野村章子、小寺政人、小野田 晃、林 高史、人見 穣
    11/9/2019~11/10/2019, 奈良
  • 第13回バイオ関連化学シンポジウム
    "蛋白質と金属錯体との複合化による酸化触媒の開発", ポスター発表
    菅井 優希、上野夏奈子、加藤俊介、野村章子、小寺政人、小野田 晃、林 高史、人見 穣
    9/4/2019~9/6/2019, 宮城
  • The 54th Japanese Peptide Symposium
    "Development of Artificial Bleomycin Analogue: Pentadentate Carboxamide Ligand Having Spermine Moiety for DNA Binding", ポスター発表
    Nomura, A.; Sakai, S.; Iwamoto, Y.; Kodera, M.; *Hitomi, Y.
    11/20/2017~11/22/2017, Osaka
  • The 67th Conference of Japan Society of Coordination Chemistry
    "Aerobic Oxidation Catalyzed by Mononuclear Non-heme Iron Complexes", ポスター発表
    Takebayashi, H.; Sakai, R.; Morikawa, N.; Hiramatsu, M.; Kodera, M.; Sasano, Y.; Iwabuchi, Y.; *Hitomi, Y.
    9/16/2017~9/18/2017, Sapporo
  • 第11回バイオ関連シンポジウム
    "鉄ブレオマイシン機能モデル錯体を用いた酸素の還元的活性化による酸化的DNA切断", ポスター発表
    Nomura, A.; Okuda, N.; Iwamoto, Y.; Kato, S.; Kodera, M.; Onoda, A.; Hayashi, T.; Hitomi, Y.
    9/7/2017~9/9/2017, 東京都