Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Ken Motokura » Japanese

Affiliation Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology
Position Associate Professor
Contact Email
HP http://search.star.titech.ac.jp/titech-ss/lang.act?forward=pursuer.act?from=outside&lang=en&&ssToken=14309dd509163f429103dab6bd892eec_IgRqNPZHIa&key_t2r2Rid=CTT100566039
Speciality Catalysis
Keyword Heterogeneous Catalysis, Solid Surface, Metal Complex, Organic Functionality, Concerted Catalysis
Institute Catalysis Society of Japan, The Chemical Society of Japan, The Japan Petroleum Institute, Japan Association of Zeolite, The Clay Science Society of Japan, American Chemical Society

Abstract

Precise Design of Catalytic Surface with Multi-active Sites through the “Site-Isolation” Concept

Achievement

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Original papers

  • "Multifunctional Catalytic Surface Design for Concerted Acceleration of One-pot Hydrosilylation-CO2 Cycloaddition"
    Kei Usui, Kodai Miyashita, Kyogo Maeda, Yuichi Manaka, Wang-Jae Chun, Koji Inazu, Ken Motokura*
    Organic Letters, 2019, 21, 9372-9376
  • "Silica-supported Alkylammonium Formate Catalyst for Hydrosilylation of Carbon Dioxide"
    Ria Ayu Pramudita, Chihiro Nakagawa, Yuichi Manaka, Ken Motokura*
    Chemistry Letters, 2019, 48, 1417-1420
  • "Unexpected Formation of Triphenylborane from Phenylboronic Acid and Its Use as an Intermediate in Palladium-Catalyzed Cross Coupling Reaction"
    Ken Motokura*, Takuma Fukuda, Yuichi Manaka
    ChemistrySelect, 2019, 4, 10501-10505
  • "Recent Advances on Heterogeneous Metal Catalysts for Hydrosilylation of Olefins"
    Kyogo Maeda, Ken Motokura*
    Journal of the Japan Petroleum Institute, 2020, 63, 1-9
  • "Carbon Dioxide to Organic Compounds Assisted by Silanes: Successive Transformation of Silyl Formate to Various Products"
    Ken Motokura*, Ria Ayu Pramudita, Yuichi Manaka
    Journal of the Japan Petroleum Institute, 2019, 62, 255-263
  • "Formate-Catalyzed Selective Reduction of Carbon Dioxide to Formate Products Using Hydrosilanes"
    Ken Motokura*, Chihiro Nakagawa, Ria Ayu Pramudita, Yuichi Manaka
    ACS Sustainable Chemistry & Engineering, 2019, 7, 11056-11061
  • "Influence of a Co-Immobilized Tertiary Amine on the Structure and Reactivity of a Rh Complex: Accelerating Effect on Heterogeneous Hydrosilylation"
    Kyogo Maeda, Yohei Uemura, Minjune Kim, Kiyotaka Nakajima, Shinji Tanaka, Wang-Jae Chun, Ken Motokura*
    The Journal of Physical Chemistry C, 2019, 123, 14556-14563
  • "Rh-catalyzed 1,4-addition reactions of arylboronic acids accelerated by co-immobilized tertiary amine in silica mesopores"
    Ken Motokura*, Kohei Hashiguchi, Kyogo Maeda, Masayuki Nambo, Yuichi Manaka, Wang-Jae Chun
    Molecular Cataysis, 2019, 472, 1-9
  • "Efficient Conversion of Carbon Dioxide with Si-based Reducing Agents Catalyzed by Metal Complexes and Salts"
    *Ken Motokura, Ria Ayu Pramudita
    The Chemical Record, 2019, 19, 1199-1209
  • "Variable-Temperature XAFS Analysis of SiO2-Supported Pd-Bisphosphine Complexes with/without Co-Immobilized Organic Functionality"
    *Ken Motokura, Yohei Uemura, Wang-Jae Chun
    Topics in Catalysis, 2018, 61, 1408-1413
  • "Silica Support-Enhanced Pd-Catalyzed Allylation using Allylic Alcohols"
    *Ken Motokura, Marika Ikeda, Minjune Kim, Kiyotaka Nakajima, Sae Kawashima, Masayuki Nambo, Wang-Jae Chun, Shinji Tanaka
    ChemCatChem, 2018, 10, 4536-4544
  • "Transformative Reduction of Carbon Dioxide through Organocatalysis with Silanes"
    Ria Ayu Pramudita, *Ken Motokura
    Green Chemistry, 2018, 20, 4834-4843
  • "Concerted Catalysis in Tight Spaces: Palladium‐Catalyzed Allylation Reactions Accelerated by Accumulated Active Sites in Mesoporous Silica"
    *Motokura, K.; Ikeda, M.; Nambo, M.; Chun, W.-J.; Nakajima, K.; Tanaka, S.
    ChemCatChem, 2017, 9, 2924-2929
  • "Effects of Mesopore Internal Surfaces on the Structure of Immobilized Pd-Bisphosphine Complexes Analyzed by Variable-Temperature XAFS and Their Catalytic Performances"
    *Ken Motokura, Takuma Fukuda, Yohei Uemura, Daiju Matsumura, Marika Ikeda, Masayuki Nambo, Wang-Jae Chun
    Catalysts, 2018, 8, 106
  • "SiO2-Supported Rh Catalyst for Efficient Hydrosilylation of Olefins Improved by Simultaneously Immobilized Tertiary Amines"
    Ken Motokura, Kyogo Maeda, Wang-Jae Chun
    ACS Catalysis, 2017, 7, 4637-4641
  • "Catalytic Processes for Utilizing Carbohydrates derived from Algal Biomass"
    Sho Yamaguchi, Ken Motokura, Kan Tanaka, Sousuke Imamura
    Catalysts, 2017, 7, 163
  • "Concerted Catalysis in Tight Spaces: Palladium-Catalyzed Allylation Reactions Accelerated by Accumulated Active Sites in Mesoporous Silica"
    Motokura, K.; Ikeda, M.; Nambo, M.; Chun, W.-J.; Nakajima, K.; Tanaka, S.
    ChemCatChem, 2017, 9, 2924-2929
  • "Reductive Transformation of CO2: Fluoride-Catalyzed Reactions with Waste Silicon-Based Reducing Agents"
    Motokura, K.; Naijo, M.; Yamaguchi, S.; Miyaji, A.; Baba, T.
    Chinese Journal of Catalysis, 2017, 38, 434-439
  • "Development of Multi-Active Site Catalysts for Surface Concerted Catalysis Aimed at One-Pot Synthesis"
    Ken Motokura
    Bulletin of the Chemical Society of Japan, 2017, 90, 137-147
  • "A Pd-Bisphosphine Complex and Organic Functionalities Immobilized on the Same SiO2 Surface: Detailed Characterization and Its Use as an Efficient Catalyst for Allylation"
    Ken Motokura, Koki Saitoh, Hiroto Noda, Wang-Jae Chun, Akimitsu Miyaji, Sho Yamaguchi, Toshihide Baba
    Catalysis Science & Technology, 2016, 6, 5380-5388

Conference

  • 4th International Symposium on Precisely Designed Catalysts with Customized Scaffolding
    "Accelerating Effect of co-Immobilized Organic Functionality on Rh Complex-Catalyzed Heterogeneous Hydrosilylation", Poster Presentation
    Ken Motokura, Kyogo Maeda, Shinji Tanaka, Kiyotaka Nakajima
    12/2019~12/2019, Nara, Japan
  • 4th International Symposium on Precisely Designed Catalysts with Customized Scaffolding
    "Homogeneous and Heterogeneous Organocatalysts for Carbon Dioxide Reduction with Silicon Based Reducing Agents", Poster Presentation
    Chihiro Nakagawa, Ria Ayu Pramudita, Yuichi Manaka, Ken Motokura
    12/2019~12/2019, Nara, Japan
  • MATERIALS RESEARCH MEETING
    "Concerted Catalysis of Designed Active Sites on Solid Surface for Highly Efficient Organic Synthesis", Oral Presentation
    Ken MOTOKURA, Hiroto NODA, Yusuke WAKABAYASHI, Hiroo TAJIRI, Kyogo MAEDA, Marika IKEDA, Wang-Jae CHUN
    12/2019~12/2019, Yokohama, Japan
  • MATERIALS RESEARCH MEETING
    "Efficient Hydrosilylation Reaction using Designed Rh Site on Silica Surface", Poster Presentation
    Kyogo Maeda, Ken Motokura
    12/2019~12/2019, Yokohama, Japan
  • The International Symposium on Catalysis and Fine Chemicals 2018 (C&FC2018)
    "Promotion of Pd-catalyzed Allylation Reaction of Nucleophiles in Silica Mesopore with Base Additives", Poster Presentation
    Sae Kawashima, Masayuki Nambo, Yuichi Manaka, Ken Motokura
    11/2019~11/2019, Tokyo, Japan
  • International Symposium on Porous Materials 2019
    "Rh-Catalyzed 1,4-Addition Reaction of Phenylboronic Acid Enhanced by Mesoporous Support", Poster Presentation
    Kohe Hashiguchi, Kyogo Maeda, Masayuki Nambo, Yuichi Manaka, Wang-Jae Chun, Ken Motokura
    11/2019~11/2019, Tokyo, Japan
  • World Hydrogen Technologies Convention
    "Organocatalyst for Carbon Dioxide Reduction to Formic Acid with Silanes and Its Heterogenization Approach", Poster Presentation
    Ria Ayu Pramudita, Chihiro Nakagawa, Yuichi Manaka, Ken Motokura
    6/2019~6/2019, Tokyo, Japan
  • World Hydrogen Technologies Convention
    "Catalytic strategies for reductive transformation of carbon dioxide to formic acid using silicon based agents", Oral Presentation
    Ken Motokura, Ria Ayu Pramudita, Chihiro Nakagawa, Yuichi Manaka
    6/2019~6/2019, Tokyo, Japan
  • World Hydrogen Technologies Convention
    "Formate-catalyzed Formic Acid Synthesis from Carbon Dioxide with Silicon Based Reducing Agents", Poster Presentation
    Chihiro Nakagawa, Ria Ayu Pramudita, Yuichi Manaka, Ken Motokura
    6/2019~6/2019, Tokyo, Japan
  • 2019 Japan-China Advanced Materials and Nanotechology Symposium -2019 Tokyo Tech- Tsinghua Univ. Joint Symposium and Advanced Materials-
    "Efficient Organic Reactions by Concerted Catalysis of Metal Complexes on Silica Surface", Invited Lecture
    Ken Motokura
    3/27/2019~3/28/2019, Kyoto, Japan
  • The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
    "Concerted Catalysis of Pd Complex on Mesoporous Silica Surface for Acceleration of Allylation of Nucleophiles", Invited Lecture
    Ken Motokura, Marika Ikeda, Masayuki Nambo, Wang-Jae Chun, Kiyotaka Nakajima, Shinji Tanaka
    8/5/2018~8/10/2018, Yokohama, Japan
  • The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
    "Co-immobilization procedure of Rh complex and tertiary amine on same SiO2 surface for highly efficient hydrosilylation of olefins", Poster Presentation
    Kyogo Maeda, Ken Motokura, Yohei Uemura, Daiju Matsumura, Wang-Jae Chun
    8/5/2018~8/10/2018, Yokohama, Japan
  • The 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8)
    "Effect of Mesopore Internal Surface on Structure of Immobilized Pd-Bisphosphine Complex Analyzed by Variable-Temperature XAFS", Poster Presentation
    Takuma Fukuda, Ken Motokura, Yohei Uemura, Daiju Matsumura, Marika Ikeda, Masayuki Nambo, Wang-Jae Chun
    8/5/2018~8/10/2018, Yokohama, Japan
  • Pre-conference of TOCAT8 and the 5th International Symposium of Institute for Catalysis
    "Rh Complex and Tertiary Amine on a Same Silica Surface: Detailed Characterization and Catalysis for Hydrosilylation of Olefins", Oral Presentation
    Kyogo Maeda, Ken Motokura
    8/3/2018~8/4/2018, Sapporo, Japan
  • 2018 International Symposium on Advancement and Prospect of Catalysis Science & Technology
    "Concerted Catalysis by Immobilized Metal Complex on Silica Surface for Efficient Hydrosilylation and Allylation", Invited Lecture
    Ken Motokura
    7/25/2018~7/27/2018, Sydney, Australia
  • International CLS Forum on Photo and Catalytic Science for Sustainable Society
    "Immobilized Rh Complex and Tertiary Amine on a Same Silica Surface: Characterization and Catalysis for Efficient Hydrosilylation of Olefins", Poster Presentation
    Kyogo Maeda, Ken Motokura
    3/3/2018~3/4/2018, Tokyo, Japan
  • International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    "Immobilized Rh Complex and Tertiary Amine on a Same Silica Surface: Characterization and its Use as a Catalyst for Hydrosilylation", Poster Presentation
    Ken Motokura, Kyogo Maeda, Wang-Jae Chun
    10/28/2017~10/30/2017, Tokyo, Japan
  • International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth
    "Concerted Catalysis between Metal Complexes and Organic Amines on Surface for Significant Acceleration of Organic Synthesis", Oral Presentation
    Ken Motokura, Kyogo Maeda, Marika Ikeda, Masayuki Nambo, Wang-Jae Chun, Kiyotaka Nakajima, Shinji Tanaka
    10/28/2017~10/30/2017, Tokyo, Japan
  • 13th European Congress on Catalysis (EUROPACAT2017)
    "Concerted Catalysis by Immobilized Rh Complex and Tertiary Amine on a Same Silica Surface for Efficient Hydrosilylation of Olefins", Poster Presentation
    Ken Motokura, Kyogo Maeda, Wang-Jae Chun
    8/27/2017~8/31/2017, Florence, Italy
  • 13th European Congress on Catalysis (EUROPACAT2017)
    "Mesoporous Silica-supported Pd Complex for Allylation Reactions with Allylic Alcohol", Poster Presentation
    Ken Motokura, Marika Ikeda, Masayuki Nambo, Wang-Jae Chun, Kiyotaka Nakajima, Shinji Tanaka
    8/27/2017~8/31/2017, Florence, Italy
  • 13th European Congress on Catalysis (EUROPACAT2017)
    "Concerted Catalysis in Tight Spaces: Mesoporous Silica-supported Palladium Complex and Tertiary Amine for Allylation of Nucleophiles", Oral Presentation
    Ken Motokura, Marika Ikeda, Masayuki Nambo, Wang-Jae Chun, Kiyotaka Nakajima, Shinji Tanaka
    8/27/2017~8/31/2017, Florence, Italy
  • The International Symposium on Pure & Applied Chemistry (ISPAC) 2017
    "Supported Palladium Complex Catalyst for Allylation Reaction Accelerated by Tertiary Amine in Mesopore", Invited Lecture
    Ken Motokura
    6/8/2017~6/10/2017, Ho Chi Minh City, Viet Nam
  • 16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    "Concerted Catalysis by Immobilized Rh Complex and Tertiary Amine on SiO2 Surface for Hydrosilylation of Olefins", Poster Presentation
    Ken Motokura, Kyogo Maeda, Wang-Jae Chun
    5/15/2017~5/17/2017, Sapporo, Japan
  • 16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    "Concerted Catalysis by Pd Complex on Mesoporous Silica for Allylation Reactions with Allylic Alcohol", Poster Presentation
    Ken Motokura, Marika Ikeda, Masayuki Nambo, Wang-Jae Chun, Kiyotaka Nakajima, Shinji Tanaka
    5/15/2017~5/17/2017, Sapporo, Japan
  • 16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    "Concerted Catalysis in Mesoporous Silica: Palladium-Catalyzed Allylation Accelerated by co-Immobilized Tertiary Amine", Oral Presentation
    Ken Motokura, Marika Ikeda, Masayuki Nambo, Wang-Jae Chun, Kiyotaka Nakajima, Shinji Tanaka
    5/15/2017~5/17/2017, Sapporo, Japan
  • 7th Asia-Pacific Congress on Catalysis
    "Highly Efficient Allylation of Nucleophiles Catalyzed by Pd-Bisphosphine Complex and Organic Base Immobilized on a Same SiO2 Surface", Oral Presentation
    Ken Motokura, Koki Saitoh, Hiroto Noda, Wang-Jae Chun, Akimitsu Miyaji, Sho Yamaguchi, Toshihide Baba
    1/17/2017~1/21/2017, Mumbai, India
  • International Symposium on Catalysis and Fine Chemicals 2016
    "Concerted Catalysis between Metal Complex and Organic Function Immobilized on Same SiO2 Surface", Invited Lecture
    Ken Motokura
    11/10/2016~11/14/2016, Taipei, Taiwan
  • The 66th JSCC Symposium, Challenges for dream catalysis - Design of catalytically active centers from the concept of coordination
    "Multi-Active Site Catalysts for Heterogeneous and Homogeneous Concerted Catalysis Aimed at Efficient Organic Reactions", Invited Lecture
    Ken Motokura
    9/10/2016~9/12/2016, Fukuoka, Japan
  • 27th International Conference on Organometallic Chemistry
    "Heterogeneous Synergistic Catalysis: Silica-Supported Palladium-bisphosphine Complex and Strong Organic Base for Allylation Reactions", Oral Presentation
    Ken Motokura, Koki Saitoh, Hiroto Noda, Wang-Jae Chun, Akimitsu Miyaji, Sho Yamaguchi, Toshihide Baba
    7/17/2016~7/22/2016, Melbourne, Australia
  • The 16th International Congress on Catalysis
    "Heterogeneous Concerted Catalysis: Metal Complex and Organic Base on a Same Silica Surface for Allylation and Addition Reactions", Oral Presentation
    Ken Motokura, Hiroto Noda, Koki Saitoh, Wang-Jae Chun, Akimitsu Miyaji, Sho Yamaguchi, Toshihide Baba
    7/3/2016~7/8/2016, Beijing, China
  • Pre-symposium of 16th International Congress on Catalysis and 2rd International Symposium of Institute for Catalysis
    "Rh Complex and Tertiary Amine Immobilized on a Same SiO2 Surface: Heterogeneous Double-Activation Catalysis and Estimation of Active Site Distance Using a Probe Molecule", Oral Presentation
    Ken Motokura, Hiroto Noda, Wang-Jae Chun, Akimitsu Miyaji, Sho Yamaguchi, Toshihide Baba
    6/30/2016~7/1/2016, Sapporo, Japan

Media

  • Green Chemistry, カバーピクチャ
    「Transformative Reduction of Carbon Dioxide through Organocatalysis with Silanes」
    Ria Ayu Pramudita, Ken Motokura, 11/7/2018
  • ChemCatChem, カバーピクチャ
    「Silica Support-Enhanced Pd-Catalyzed Allylation using Allylic Alcohols」
    Ken Motokura, Marika Ikeda, Minjune Kim, Kiyotaka Nakajima, Sae Kawashima, Masayuki Nambo, Wang-Jae Chun, Shinji Tanaka, 10/24/2018
  • SYNFACTS, 雑誌記事
    「Hydrosilylation of Olefins on a Silica-Supported Rhodium/Amine Catalyst」
    Motokura, K.; Maeda, K.; Chun, W.-J., 10/19/2017
    PDF File
  • Bulletin of the Chemical Society of Japan, カバーピクチャ
    「Development of Multi-Active Site Catalysts for Surface Concerted Catalysis Aimed at One-Pot Synthesis」
    Motokura, K., 3/2017
    PDF File