Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Tetsuaki Fujihara » Japanese

Affiliation Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University
Position Associate Professor
Speciality Organometallic Chemistry, Catalysis, Coordination Chemistry, Supramolecular Chemistry
Keyword Homogeneous Catalysis, Ligand, Carbon Dioxide, Dendrimer

Abstract

Development of Periphery-Functionalized Gigantic Ligands and Their Application to Transition-Metal Catalyzed Reactions

Achievement

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Original papers

  • "Pd-​Catalyzed intermolecular C-​H bond arylation reactions: effect of bulkiness of carboxylate ligands"
    Tanji, Y.; Hamaguchi, R.; Tsuji, Y.; *Fujihara, T.
    Chem. Commun., 2020, 56, in press
  • "Pd-Catalyzed Synthesis of Fluorenes via Intramolecular C(sp2)-H Activation at Room Temperature"
    Tanji, Y.; Tsuji, Y.; *Fujihara, T.
    Synlett, 2020, 31, in press
  • "Zinc-​Catalyzed Synthesis of Acylsilanes Using Carboxylic Acids and a Silylborane in the Presence of Pivalic Anhydride"
    Tatsumi, K.; Tanabe, S.; Tsuji, Y.; *Fujihara, T.
    Org. Lett., 2019, 21, 10130-10133
  • "Cobalt-Catalyzed Reductive Coupling of Alkynes and Acrylates Bearing a Leaving Group: Construction of Cyclobutene Rings"
    *Fujihara, T.; Kukita, S,; Yagi, Y.; Kirihara, M.; Nogi, K.; *Tsuji, Y.
    Asian J. Org. Chem., 2018, 7, 2456-2458
  • "Copper-Catalyzed [4+2] Cycloaddition Using N-(2-pyridyl)Ketimines and Terminal Alkynes"
    Tatsumi, K; *Fujihara, T.; Terao, J.; *Tsuji, Y.
    Adv. Synth. Catal., 2018, 360, 3245-3248
  • "Steric Effect of Carboxylate Ligands on Pd-Catalyzed Intramolecular C(sp2)–H and C(sp3)–H Bond Arylation Reactions"
    Tanji, Y.; Mitsutake, N.; *Fujihara, T.; *Tsuji, Y.
    Angew. Chem. Int. Ed., 2018, 57, 10314-10317
  • "Copper-Catalyzed Bora-acylation and Bora-alkoxyoxalylation of Allenes"
    Sawada, A.; *Fujihara, T.; *Tusji, Y.
    Adv. Synth. Catal., 2018, 360, 2621-2625
  • "Synthesis and Characterization of Carboxylic Acids Bearing Poly(ethylene glycol) Chains"
    Satou, M.; *Fujihara,T.; Terao, J.; *Tsuji, Y.
    Synlett, 2018, 29, 556-559
  • "Copper-Catalyzed Hydroallylation of Allenes Employing Hydrosilanes and Allyl Chlorides"
    *Fujihara, T.; Yokota, K.; Terao, J.; *Tsuji, Y.
    Chem. Commun., 2017, 53, 7898-7900
  • "Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide Catalyzed by MgCl2"
    Fujihara, T.; Inokuchi, M.; Mizoe, T.; Nogi, K.; Terao, J.; Tsuji, Y.
    Chem. Lett., 2017, 46, 968-969
  • "Boraformylation and Silaformylation of Allenes"
    *Fujihara, T.; Sawada, A.; Yamaguchi, T.; Tani, Y.; Terao, J.; *Tsuji, Y.
    Angew. Chem. Int. Ed., 2017, 56, 1539-1543
  • "Steric Effect of Carboxylic Acid Ligands on Pd-catalyzed C-H Activation Reactions"
    Fujihara, T.; Yoshida, A.; Satou, M.; Tanji, Y.; Terao, J.; Tsuji, Y.
    Catal. Commun., 2016, 84, 71-74
  • "Carboxyzincation Employing Carbon Dioxide and Zinc Powder: Cobalt-Catalyzed Multicomponent Coupling Reactions with Alkynes"
    Nogi,K.; Fujihara,T.; Terao,J.; Tsuji, Y.
    J. Am. Chem. Soc., 2016, 138, 5547-5550

Review

  • 「Carboxylation Reactions Using Carbon Dioxide as the C1 Source via Catalytically Generated Allyl Metal Intermediates」 *Fujihara, T.; Tsuji, Y., Front. Chem., 7, Article 430, 2019
  • 「Cobalt- and Rhodium-Catalyzed Carboxylation Using Carbon Dioxide as the C1 Source」 Fujihara, T.; Tsuji, Y., Beilstein J. Org. Chem., 14, 2435-2460, 2018
  • 「Transition-Metal-Catalyzed Synthesis of Carbonyl Compounds Using Formates or Formamides as Carbonyl Sources 」 Fujihara, T.; Tsuji, Y., J. Jpn. Petrol. Inst., 61, 1-9, 2018
  • 「Cu-catalyzed Borylative and Silylative Transformations of Allenes: Use of beta-Functionalized Allyl Copper Intermediates in Organic Synthesis」 Fujihara, T.; Tsuji, Y., Synthesis, 50, 1737-1749, 2018
  • 「Copper-Catalyzed Transformations Using Cu-H, Cu-B and Cu-Si as Active Catalyst Species」 Tsuji, Y.; Fujihara, T., Chem. Rec., 16, 2294-2313 , 2016
  • 「Transition-Metal-Catalyzed Fixation of Carbon Dioxide via Carbon-Carbon Bond Formation」 Fujihara, T.; Tsuji, Y., J. Jpn. Petrol. Inst., 59, 84-92, 2016

Conference

  • International Symposium on Catalysis and Fine Chemicals 2018
    "Cobalt-Catalyzed Carboxylation Reactions Using Carbon Dioxide as the C1 Source", Invited Lecture
    Fujihara, T.
    12/14/2018~12/14/2018, Bangkok, Thailand
  • International Symposium on Catalysis and Fine Chemicals 2016
    "Copper-Catalyzed Silacarboxylation of Alkynes and Allenes Using Carbon Dioxide and a Silylborane", Invited Lecture
    Fujihara, T.; Tani, Y.; Terao, J.; Tsuji, Y.
    11/10/2016~11/14/2016, Taipei, Taiwan
  • 20th The International Symposium on Homogeneous Catalysis
    "Carboxyzincation Employing Carbon Dioxide and Zinc Powder: Cobalt-Catalyzed Multicomponent Coupling Reactions with Alkynes", Oral Presentation
    Fujihara, T.; Nogi, K.; Terao, J.; Tsuji, Y.
    7/10/2016~7/16/2016, Kyoto, Japan

Media

  • Chem. Commun., カバーピクチャ
    Tanji, Y.; Hamaguchi, R.; Tsuji, Y.; *Fujihara, T., 3/2020
    PDF File
  • Asian J. Org. Chem., カバーピクチャ
    Fujihara, T.; Kukita, S,; Yagi, Y.; Kirihara, M.; Nogi, K.; Tsuji, Y., 12/2018
    PDF File
  • Chem. Commun., カバーピクチャ
    「Copper-Catalyzed Hydroallylation of Allenes Employing Hydrosilanes and Allyl Chlorides」
    Fujihara, T.; Yokota, K.; Terao, J.; Tuuji, Y., 7/2017
    PDF File
  • Angew. Chem. Int. Ed., カバーピクチャ
    「Boraformylation and Silaformylation of Allenes」
    Fujihara, T.; Sawada, A.; Yamaguchi, T.; Tani, Y.; Terao, J.; Tsuji, Y., 2/2017
    PDF File