Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Sensuke Ogoshi » Japanese

Affiliation Department of Applied Chemistry, Graduate School Engineering, Osaka University
Position Professor
HP http://www.chem.eng.osaka-u.ac.jp/~ogoshi-lab/

Abstract

◆Research Topics:
Molecular Transformation in Variable Volume Reaction Site

◆Research:

Achievement

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Original papers

  • "Axial Chirality around N-P Bonds Induced by Complexation betwen E(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> (E = B, Al) and an N-Phosphine-Oxide-Substituted Imidazolinylidene: A Key Intermediate in the Catalytic Phosphinoylation of CO<sub>2</sub>"
    Asada, T.; *Hoshimoto, Y.; Kawakita, T.; Kinoshita, T.; *Ogoshi, S.
    The Journal of Organic Chemistry, 2020, ASAP, ASAP
  • "Enantioselective Synthesis of Polycyclic γ-Lactams with Multiple Chiral Carbon Centers via Ni(0)-Catalyzed Asymmetric Carbonylative Cycloadditions without Stirring"
    Ashida, K.; Hoshimoto, Y.; Tohnai, N.; Scott, D.; Ohashi, M.; Imaizumi, H.; Tsuchiya, Y.; *Ogoshi, S.
    Journal of the American Chemical Society, 2020, 142(3), 1594-1602
  • "Nickel-Catalyzed Decarbonylation of N-Acylated N-Heteroarenes"
    Morioka, T.; Nakatani, S.; Sakamoto, Y.; Kodama, T.; Ogoshi, S.; Chatani, N.* Tobisu, M.*
    Chem. Sci., 2019, 10, 6666-6671
  • "Catalytic Synthesis of Isoquinolines via Intramolecular Migration of N-Aryl Sulfonyl Groups on 1,5-Yne-Imines"
    Hoshimoto, Y.; Nishimura, C.; Sasaoka, Y.; Kumar, R.; *Ogoshi, S.
    Bulletin of the Chemical Society of Japan , 2020, 93(2), 182-186
  • "Nickel-catalyzed decarbonylation of N-acylated N-heteroarenes"
    Morioka, T.; Nakatani, S.; Sakamoto, Y.; Kodama, T.; Ogoshi, S.; *Chatani, N.; *Tobisu, M.
    Chemical Science, 2019, 10, 6666-6671
  • "Triarylborane-Catalyzed Reductive N-Alkylation of Amines: A Perspective"
    *Hoshimoto, Y.; *Ogoshi, S.
    ACS Catal., 2019, 9(6), 5439-5444
  • "Ni(0)-Catalyzed Three-Component Coupling Reaction of Tetrafluoroethylene and N-Sulfonyl-Substituted Imines with Silanes via Aza-Nickelacycles"
    Shirataki, H.; Ono, T.; *Ohashi, M.; *Ogoshi, S.
    Organic Letters, 2019, 21, 851-856
  • "Complexation between MOTf (M = Li and Na) and N-Phosphine Oxide-substituted Imidazolylidenes via Coordination of the N-Phosphoryl Groups"
    Kinoshita, T.; Sakuraba, M.; *Hoshimoto, Y.; *Ogoshi, S.
    Chemistry Letters, 2019, 48, 230-233
  • "Nickel-catalyzed Three-component Coupling Reaction of Tetrafluoroethylene and Aldehydes with Silanes via Oxa-Nickelacycles"
    Shirataki, H.; *Ohashi, M.; *Ogoshi, S.
    European Journal of Organic Chemistry, 2019, 9, 1883-1887
  • "Selective Catalytic Formation of Cross-Tetramers from Tetrafluoroethylene, Ethylene, Alkynes, and Aldehydes via Nickelacycles as Key Reaction Intermediates "
    *Kawashima, T.; Ohashi, M.; *Ogoshi, S.
    Journal of the American Chmical Society, 2018, 140, 17423–17427
  • "Strain-Induced Double Carbon-Carbon Bond Activations of Cycloparaphenylenes by a Platinum Complex: Application to the Synthsis of Cyclic Diketones"
    *Kayahara, E.; Hayashi, T.; Takeuchi, K.; Ozawa, F.; Ashida, K., Ogoshi, S.; *Yamago, S.
    Angewandte Chemie International Edition, 2018, 57, 11418-11421
  • "Main-Group-Catalyzed Reductive Alkylation of Multiply Substituted Amines with Aldehydes Using H<sub>2</sub>"
    *Hoshimoto, Y.; Kinoshita, T.; Hazra, S.; Ohashi, M.; *Ogoshi, S.
    Journal of the American Chmical Society, 2018, 140(23), 7292–7300
  • "Cu<sup>I</sup>‐Catalyzed Pentafluoroethylation of Aryl Iodides in the Presence of Tetrafluoroethylene and Cesium Fluoride: Determining the Route to the Key Pentafluoroethyl Cu<sup>I</sup> Intermediate "
    *Ohashi, M.; Ishida, N.; Ando, K.; Hashimoto, Y.; Shigaki, A.; Kikushima, K.; *Ogoshi, S.
    Chemistry A European Journal, 2018, 24(39), 9794-9798
  • "Highly Atom Economical Molecular Transformation via Hetero-Nickelacycle "
    *Ogoshi, S.
    Bull. Chem. Soc. Jpn., 2017, 90(12), 1401-1406
  • "Nickel-Catalyzed Formation of 1,3-Dienes via a Highly Selective Cross-Tetramerization of Tetrafluoroethylene, Styrenes, Alkynes, and Ethylene"
    Kawashima, T.; *Ohashi, M.; *Ogoshi, S.
    Journal of the American Chemical Society, 2017, 139(49), 17795–17798
  • "Fluorinated Vinylsilanes from the Copper-Catalyzed Defluorosilylation of Fluoroalkene Feedstocks"
    Sakaguchi, H.; Ohashi, M.; *Ogoshi, S.
    Angewandte Chemie International Edition, 2017, 57, 328 –332
  • "Transition-metal-free catalytic hydrodefluorination of polyfluoroarenes via a concerted nucleophilic aromatic substitution with a hydrosilicate"
    Kikushima, K.; Grellier, M.; Ohashi, M.; *Ogoshi, S.
    Angewandte Chemie International Edition, 2017, 56(51), 16191–16196
  • "N-Phosphine Oxide-Substiuted Imidazolylidenes (PoxIms): Multifunctional Multipurpose Carbenes"
    Hazra, S.; *Hoshimoto, Y.; *Ogoshi, S.
    Chemistry - A European Journal, 2017, 23(61), 15238–15243
  • "Copper-Catalyzed Regioselective Monodefluoroborylation of Polyfluoroalkenes en Route to Diverse Fluoroalkenes "
    Sakaguchi, H.; Uetake, Y.; Ohashi, M.; *Niwa, T.; *Ogoshi, S.; *Hosoya, T.
    Journal of the American Chemical Society, 2017, 139(36), 12855-12862
  • "Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroehtylene"
    Ohashi, M.; Adachi, T.; Ishida, N.; Kikushima, K.; *Ogoshi, S.
    Angewandte Chemie International Edition, 2017, 56, 11911–11915
  • "Phosphorylation of Isocyanates and Aldehydes Mediated by Multifunctional N-Phosphine Oxide-Substituted Imidazolylidenes"
    *Hoshimoto, Y.; Asada, T.; Hazra, S.; Ohashi, M.; *Ogoshi, S.
    Chemistry Letters, 2017, 46(8), 1211-1213
  • "Nickel(0)-Catalyzed Coupling Reactions of Carbonyls and Alkenes with Reducing Reagents Giving Six- and Seven-Membered Benzocycloalkanols"
    Hayashi, Y.; Hoshimoto, Y.; Ravindr, K.; Ohashi, M.; *Ogoshi, S.
    Chemistry Letters, 2017, 46(8), 1096-1098
  • "Two-step synthesis of chiral fused tricyclic scaffolds from phenols via desymmetrization on nickel"
    Kumar, R.; Hoshimoto, Y.; Tamai, E.; Ohashi, M, *Ogoshi, S.
    Nature Communications, 2017, 8(32), 1-7
  • "Efficient Synthesis of Polycyclic γ-Lactams by Catalytic Carbonylation of Ene-Imines via Nickelacycle Intermediates"
    Hoshimoto,Y.; Ashida, K.; Sasaoka, Y.; Kumar, R.; Kamikawa,K.; Verdaguer,X.; Riera,A.; Ohashi,M.; Ogoshi, S.
    Angew. Chem. Int. Ed., 2017, 56, in press
  • "Efficient Synthesis of Polycyclic γ-Lactams by Catalytic Carbonylation of Ene-Imines via Nickelacycle Intermediates"
    Hoshimoto, Y,; Ashida, K.; Sasaoka, Y.; Kumar, R.; Kamikawa, K.; Verdaguer, X.; Riera, A.; Ohashi, M.; *Ogoshi, S.
    Angewandte Chemie International Edition, 2017, 56(28), 8206–8210
  • "Copolymerisation of Ethylene with Polar Monomers by Palladium Catalysts Bearing an N-Heterocyclic Carbene–Phosphine Oxide Bidentate Ligand"
    Tao, W.; Akita, S.; Nakano, R.; Ito, S.; Hoshimoto, Y.; Ogoshi, S.; Nozaki, K.
    Chem. Commun., 2017, 53, 2630–2633
  • "Copolymerisation of Ethylene with Polar Monomers by Palladium Catalysts Bearing an N-Heterocyclic Carbene–Phosphine Oxide Bidentate Ligand"
    Tao, W.; Akita, S.; Nakano, R.; Ito, S.; Hoshimoto, Y.; Ogoshi, S.; Nozaki, K.
    Chem. Commun., 2017, 53, 2630–2633
  • "Copolymerisation of ethylene with polar monomers by using palladium catalysts bearing an N-heterocyclic carbene-phosphine oxide bidentate ligand"
    Tao, W.; Akita, S.; Nakano, R.; Ito, S.; Hoshimoto, Y.; Ogoshi, S.; *Nozaki, K.
    Chemical Communications, 2017, 53(17), 2630-2633
  • "Nickel(0)-Mediated Transformation of Tetrafluoroethylene and Vinylarenes into Fluorinated Cyclobutyl Compounds"
    *Ohashi, M.; Ueda, Y.; *Ogoshi, S.
    Angewandte Chemie International Edition, 2017, 56(9), 2435–2439
  • "Kinetic and Theoretical Studies on Ni(0)/N-Heterocyclic Carbene-Catalyzed Intramolecular Alkene Hydroacylation"
    Hoshimoto, Y.; Hayashi, Y.; Ohashi, M.; *Ogoshi, S.
    Chemistry – An Asian Journal, 2017, 12(3), 278–282
  • "Strategic Utilization of Multifunctional Carbene for Direct Synthesis of Carboxylic–Phosphinic Mixed Anhydride from CO2"
    *Hoshimoto, Y.; Asada, T.; Hazra, S.; Kinoshita, T.; Sombut, P.; Kumar, R.; Ohashi, M.; *Ogoshi, S.
    Angewandte Chemie International Edition, 2016, 55(52), 16075–16079
  • "Ni(0)-catalyzed intramolecular reductive coupling of alkenes and aldehydes or ketones with hydrosilane"
    Hayashi, Y.; Hoshimoto, Y.; Kumar, R.; Ohashi, M.; *Ogoshi, S.
    Chemical Communications, 2016, 52(37), 6237-6240
  • "Nickel-Catalyzed Enantioselective Synthesis of Cyclobutenes via [2+2] Cycloaddition of α,β-Unsaturated Carbonyls with 1,3-Enynes"
    Kumar, R.; Tamai, E.; Ohnish, A.; Nishimura, A.; Hoshimoto, Y.; Ohashi, M.; *Ogoshi, S.
    Synthesis, 2016, 48(17), 2789-2794
  • "Nickel(0)/N‐Heterocyclic Carbene-Catalyzed Asymmetric [2 + 2 + 2] Cycloaddition of Two Enones and an Alkyne: Access to Cyclohexenes with Four Contiguous Stereogenic Centers"
    Kumar, T.; Tokura, H.; Nishimura, A.; Mori, T.; Hoshimoto, Y.; Ohashi, M.; *Ogoshi, S.
    Organic Letters, 2015, 17, 6018−6021
  • "Copper-Catalyzed Reaction of Trifluoromethylketones with Aldehydes via a Copper Difluoroenolate"
    Doi, R.; Ohashi, M.; *Ogoshi, S.
    Angewandte Chemie International Edition, 2016, 55(1), 341-344
  • "A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes"
    *Hoshimoto, Y.; Kinoshita, T.; Ohashi, M.; *Ogoshi, S.
    Angewandte Chemie International Edition, 2015, 54(40), 11666-11671
  • "Nickel-Catalyzed Formation of Fluorine-Containing Ketones via the Selective Cross-Trimerization Reaction of Tetrafluoroethylene, Ethylene, and Aldehydes"
    *Ohashi, M.; Shirataki, H.; Kikushima, K.; *Ogoshi, S.
    Journal of the American Chemical Society, 2015, 137(20), 6496-6499
  • "2,2,3,3-Tetrafluoronickelacyclopentanes Generated via the Oxidative Cyclization of Tetrafluoroethylene and Simple Alkenes: A Key Intermediate in Nickel-Catalyzed C-C Bond-Forming Reactions"
    *Ohashi, M.; Kawashima, T.; Taniguchi, T. O.; Kikushima, K.; *Ogoshi, S.
    Organometallics, 2015, 34(9), 1604-1607
  • "Aza-nickelacycle key intermediate in nickel(0)-catalyzed transformation reactions"
    Ohashi, M.; Hoshimoto, Y.; *Ogoshi, S.
    Dalton Transactions, 2015, 44(27), 12060-12073
  • "Nickel(0)-Catalyzed Enantio- and Diastereoselective Synthesis of Benzoxasiloles: Ligand-Controlled Switching from Inter- to Intramolecular Aryl-Transfer Process"
    Kumar, R.; Hoshimoto, Y.; Yabuki, H.; Ohashi, M.; *Ogoshi, S.
    Journal of the American Chemical Society, 2015, 137(36), 11838-11845
  • "Copper-mediated One-pot Synthesis of Trifluorostyrene Derivatives from Tetrafluoroethylene and Arylboronate"
    Kikushima, K.; Sakaguchi, H.; Saijo, H.; *Ohashi, M.; *Ogoshi, S.
    Chemistry Letters, 2015, 44(7), 1019-1021

Review

  • 「Catalytic Transformation of Aldehydes with Nickel Complexes through η2 Coordination and Oxidative Cyclization」 Hoshimoto, Y.; Ohashi, M.; Ogoshi, S, Accounts of Chemical Research, 48, 1746-1755, 6, 2015

Conference

  • 4th International Symposium on Precisely Designed Catalysts with Customized Scaffolding
    "Nickel-catalyzed Synthesis of Benzoxasiloles: Ligand-Controlled Switchingfrom Inter- to Intramolecular Aryl-Transfer Process", Poster Presentation
    Ogoshi, S.
    12/3/2019~12/5/2019, Nara, Japan
  • 4th International Symposium on Precisely Designed Catalysts with Customized Scaffolding
    "Enantioselective Synthesis of Chiral γ-Lactams by Ni(0)-CatalyzedAsymmetric Carbonylative Cycloaddition", Poster Presentation
    Ashida, K.; Hoshimoto, Y.; Ogoshi, S.
    12/3/2019~12/5/2019, Nara, Japan
  • The 2nd Japan Germany Singapore Trilateral Symposium on Precision Synthesis and Catalysis
    "Nickel-Catalyzed Multi Components CouplingReaction of Tetrafluoroethylene, Ethylene, and More", Invited Lecture
    Ogoshi, S.
    12/2/2019~12/3/2019, Nara, Japan
  • the 14th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-14)
    "Nickel-catalyzed Three-component Coupling Reaction of Tetrafluoroethylene and Aldehydes with Silanes via Oxa-Nickelacycles", Oral Presentation
    Ogoshi, S.
    9/26/2019~9/29/2019, Sapporo, Japan
  • 27th International Society of Heterocyclic Chemistry Congress(ISHC)
    "Nickel-catalyzed Synthesis of Benzoxasiloles: Ligand-Controlled Switching from Inter- to Intramolecular Aryl-Transfer Process", Oral Presentation
    Ogoshi, S.
    9/1/2019~9/6/2019, Kyoto, Japan
  • 27th International Society of Heterocyclic Chemistry Congress(ISHC)
    "Catalytic Synthesis of Isoquinolines from 1,5-Yne-Imines through Migration of N-Aryl Sulfonyl Groups", Poster Presentation
    Nishimura, C.; Hoshimoto, Y.; Ogoshi.
    9/1/2019~9/6/2019, Kyoto, Japan
  • 27th International Society of Heterocyclic Chemistry Congress(ISHC)
    "Cu(I)-Catalyzed Pentafluoroethylation of Aryl Iodides Using Tetrafluoroethylene and CsF", Poster Presentation
    Ishida, N.; Ando, K.; Hashimoto, Y.; Shigaki, A.; Kikushima, K.; Ohashi, M.; Ogoshi, S.
    9/1/2019~9/6/2019, Kyoto, Japan
  • 27th International Society of Heterocyclic Chemistry Congress(ISHC)
    "Complexation between Lewis Acids and N-Phosphine Oxide-substituted Imidazolylidenes (PoxIms)", Poster Presentation
    Sakuraba, M.; Hoshimoto, Y.; Ogoshi, S.
    9/1/2019~9/6/2019, Kyoto, Japan
  • 27th International Society of Heterocyclic Chemistry Congress(ISHC)
    "Complexation between Al(C6F5)3 and N-Phoshpnine Oxide-Substituted Imidazolidenes", Oral Presentation
    Asada, T.; Hoshimoto, Y.; Ogoshi, S.
    9/1/2019~9/6/2019, Kyoto, Japan
  • 27th International Society of Heterocyclic Chemistry Congress(ISHC)
    "Enantioselective Synthesis of Chiral γ-Lactams by Ni(0)-Catalyzed Asymmetric Carbonylative Cycloaddition", Poster Presentation
    Ashida, K.; Hoshimoto, Y.; Ogoshi, S.
    9/1/2019~9/6/2019, Kyoto, Japan
  • ACS Fall 2019 National Meeting & Exposition
    "Cu(I)-catalyzed pentafluoroethylation of aryl iodides in the presence of tetrafluoroethylene and CsF", Poster Presentation
    Naoyoshi Ishida, Kota Ando, Yu Hashimoto, Anna Shigaki, Kotaro Kikushima, Masato Ohashi, Sensuke Ogoshi
    8/25/2019~8/29/2019, San Diego, USA
  • ACS Fall 2019 National Meeting & Exposition
    "Phosphorylation of carbon-oxygen bond mediated by N-phosphine oxide-substituted imidazolylidenes", Poster Presentation
    Asada, T.; Hoshimoto, Y.; Ogoshi, S.
    8/25/2019~8/29/2019, San Diego, USA
  • ACS Fall 2019 National Meeting & Exposition
    "Enantioselective Formation of γ-Lactams with Multiple Chiral Carbon Centers by Ni(0)-Catalyzed Asymmetric Carbonylative Cycloaddition", Poster Presentation
    Ashida, K.; Hoshimoto, Y.; Ogoshi, S.
    8/25/2019~8/29/2019, San Diego, USA
  • The International Symposium on Organic Reactions (ISOR-13)
    "Base Metal-Catalyzed Reactions of Gaseous Reactant Under No Stirring Condition", Invited Lecture
    Ogoshi, S
    11/21/2018~11/24/2018, Hsinchu, Taiwan
  • Pre-International Symposium on Organic Reaction
    "Nickel-Catalyzed Three-Component Coupling Reaction of Tetrafluoroethylene and Aldehydes with Silanes", Invited Lecture
    Ogoshi, S
    11/19/2018~11/21/2018, Taipei, Taiwan
  • The 14th International KYOTO conference on New Aspests of Organic Chemistry (IKCOC-14)
    "Ni(0)-Catalyzed Unprecedented Highly Selective Cross-Tetramerization of Tetrafluoroethylene, Ethylene, Alkynes, and Aldehydes", Poster Presentation
    Kawashima, T.; Ohashi, M.; Ogoshi, S.
    11/13/2018~11/15/2018, Kyoto, Japan
  • The 18th JAPAN-KOREA Joint Sumposium on Organometallic and Coordination Chemistry
    "PoxIms: Multifunctional multipurpose Carbenes", Poster Presentation
    Hoshimoto, Y.; Kinoshita, T.; Asada, T.; Hazra, S.; Ogoshi, S.
    10/31/2018~11/2/2018, Yokkaichi, Japan
  • The 4th International Symposium on C-H Activation
    "Nickel-Catalyzed Formation of Fluorine-Containing Ketones via Chemoselective Cross-Trimerization Reaction of Tetrafluoroethylene, Ethylene, and Aldehydes ", Poster Presentation
    Shirataki, H.; Kikushima, K.; Ohashi, M.; Ogoshi, S.
    8/30/2018~9/2/2018, Yokohama, Japan
  • the 22nd International Symposium on Fluorine Chemistry (ISFC22)
    "Ni(0)-Catalyzed Highly Selective Cross-Tetramerizations of Tetrafluoroethylene with Various Unsaturated Compounds", Poster Presentation
    Kawashima, T.; Ohashi, M.; Ogoshi, S.
    7/23/2018~7/27/2018, Oxfotd, United Kingdom
  • the 28th International Conference on Organometallic Chemistry (ICOMC-2018)
    "Nickel-catalyzed Asymmetric Reaction via Oxidative Cyclization with Full Control over Multiple StereogenicCenters", Invited Lecture
    Ogoshi, S
    7/15/2018~7/20/2018, Florence, Italy
  • the 28th International Conference on Organometallic Chemistry (ICOMC-2018)
    "Nickel-Catalyzed Three-Component Coupling Reaction of Tetrafluoroethylene and Aldehydes with Silanes", Poster Presentation
    Shirataki, H.; Ohashi, M.; Ogoshi, S.
    7/15/2018~7/20/2018, Florence, Italy
  • the 28th International Conference on Organometallic Chemistry (ICOMC-2018)
    "Efficient Synthesis of Polycyclic γ-Lactams by Ni(0)-Catalyzed [2+2+1] Cycloaddition of Ene-Imines with Carbon Monoxide", Poster Presentation
    Ashida, K.; Hoshimoto, Y.; Ohashi, M.; Ogoshi, S.
    7/15/2018~7/20/2018, Florence, Italy
  • the 28th International Conference on Organometallic Chemistry (ICOMC-2018)
    "Strategic Use of N-Phosphine Oxide-Substituted Imidazolylidenes for Phosphorylation of Carbon-Oxygen Bond", Poster Presentation
    Asada, T.; Hazra, S.; Hoshimoto, Y.; Ogoshi, S.
    7/15/2018~7/20/2018, Florence, Italy
  • 21st International Symposium on Homogeneous Catalysis
    "Nickel or Cupper-Catalyzed Reactions of Gaseous Reactant Under No Stirring Condition", Keynote Lecture
    Ogoshi, S
    7/8/2018~7/13/2018, Amsterdam, The Netherlands
  • Chem. Sci., カバーピクチャ
    「CuCl/TMEDA/nor-AZADO-catalyzed aerobic oxidative acylation of amides with alcohols to produce imides」
    Kataoka, K.; Wachi, K., *Jin, X.; Suzuki, K.; Sasano, Y.; Iwabuchi, Y.; Hasegawa, J.; Mizuno, N.; *Yamaguchi, K., 5/7/2018
    PDF File
  • The12th International Conference on Cutting-edge Organic Chemistry inAsia(ICCEOCA-12)
    "Enantioselective Desymmetrization Strategy by Oxidative Cyclization on Nickel: Expedient Access to Fused Tricyclic Scaffolds", Poster Presentation
    Ogoshi, S
    11/2/2017~11/5/2017, 西安, 中国
  • The 21th International Annual Symposium on Computational Science and Engineering (ANSCSE 21)
    "Theoretical Study of Frustrated Lewis Pair for Activation of Stable Chemical Bonds", Invited Lecture
    Hasegawa, J.; Ohbo, M.; Hoshimoto, Y.; Ogoshi, S.
    8/3/2017~8/4/2017, Pathum Thani, Thailand
  • the 19th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis(OMCOS19)
    "Ni(0)-Catalyzed Intramolecular [2+2+1] Cycloaddition of Ene-Imines with Carbon Monoxide Leading to Polycyclic γ-Lactams", Poster Presentation
    Ashsida, K.; Hoshimoto, Y.; Ohashi, M.; Ogoshi, S.
    6/25/2017~6/29/2017, Jeju, Korea
  • The 12th International Conference of Heteroatom Chemistry(ICHAC-12)
    "A Frsutration Revival Strategy with Shelf-Stable Carbene-Borane Adducts", Oral Presentation
    Hoshimoto, Y.; Kinoshita, T.; Ohashi, M.; Ogoshi, S.
    6/11/2017~6/16/2017, Vancouver, Kanada
  • The 12th International Conference of Heteroatom Chemistry(ICHAC-12)
    "Copper-Catalyzed Silylation of Fluoroalkenes via C-F Bond Cleavage", Poster Presentation
    Sakaguchi, H.; Ohashi, M.; Ogoshi, S.
    6/11/2017~6/16/2017, Vancouver, Kanada
  • Catalysis and Fine Chemicals 2016 (C&FC 2016)
    "Fluorosilicate-Catalyzed Hydrodefluorination of Polyfluoroarenes", Invited Lecture
    Ogoshi, S.
    11/11/2016~11/14/2016, Taipei, Taiwan
  • 17th Korea-Japan Joint Symposium on Organometallic and Coordination Chemistry
    "Transformation of Tetrafluoroethylene by Ubiquitous Metal. Isolation and Reactivity of Intermediate Complexes ", Invited Lecture
    Ogoshi, S.
    11/3/2016~11/5/2016, Busan, Korea
  • 9th Asian-European Symposium on Metal-Mediated Efficient Organic Synthesis
    "Transformation of Tetrafluoroethylene by Transition Metal Complexes", Invited Lecture
    Ogoshi, S.
    9/4/2016~9/7/2016, Stockholm, Sweden
  • OM&Cat 2016
    "Synthesis of Perfluoroalkyl and Perfluoroalkoxy Complexes from Cu(I) Complex", Poster Presentation
    Ishida, N.; Kikushima, K.; Ohashi, M.; Ogoshi, S.
    8/28/2016~8/30/2016, Seoul, Korea
  • the 27th International Conference on Organometallic Chemistry (ICOMC 2016)
    "Ni(0)-Catalyzed Diastereoselective Three-Component Coupling of Aldehydes, Alkenes, and Hydrosilanes", Poster Presentation
    Hayashi, Y.; Hoshimoto, Y.; Ohashi, M.; Ogoshi, S.
    7/17/2016~7/22/2016, Melborne, Australia
  • the 27th International Conference on Organometallic Chemistry (ICOMC 2016)
    "Development of a Catalytic Reaction via the Oxidative Cyclization of Tetrafluoroethylene and Unsaturated Compounds with Ni(0) as a Key Step", Poster Presentation
    Kawashima, T.; Kikushima, K.; Ohashi, M.; Ogoshi, S.
    7/17/2016~7/22/2016, Melborne, Australia
  • XXVII European Colloquium on Heterocyclic Chemistry
    "Direct Preparation of Carboxylic-Phosphinic Mixed Anhydride from Carbon Dioxide and N-Phosphine Oxide Substituted Imidazolylidene", Poster Presentation
    Asada, T.; Hoshimoto, Y.; Ogoshi, S.
    7/3/2016~7/6/2016, Amsterdam, Netherlands
  • XXVII European Colloquium on Heterocyclic Chemistry
    "REVIVAL OF FRUSTRATED LEWIS PAIRS FROM SHELF-STABLE CARBENE-BORANE COMPLEXES", Poster Presentation
    Kinoshita, T.; Hoshimoto, Y.; Ogoshi, S.
    7/3/2016~7/6/2016, Amsterdam, Netherlands
  • Bremen Fluorine Days 2016
    "Hydrodefluorination of Polyfluoroaenes without Transition-Metal", Poster Presentation
    Kikushima, K.; Ohashi, M.; Ogoshi, S.
    7/3/2016~7/7/2016, Bremen, Germany
  • Fluor als Schlüsselelement
    "Tetrafluoroethylene Is Good For More Than Just Teflon", Invited Lecture
    Ogoshi, S.
    6/30/2016~7/1/2016, Berlin, Germany
  • Osaka-CCHF Joint Workshop on C-H Bond Activation
    "Cross-Trimerization of Tetrafluoroethylene, Ethylene, and Carbonyl Compounds via Nickelacycle Key Intermediate", Oral Presentation
    Shirataki, H.; Kotaro, K.; Ohashi, M.; Ogoshi, S.
    6/14/2016~6/14/2016, Osaka, Japan
  • Osaka-CCHF Joint Workshop on C-H Bond Activation
    "Ni(0)-Catalyzed Intramolecular Reductive Coupling of Aldehydes and Alkenes with Hydrosilanes", Oral Presentation
    Hayashi, Y.; Hoshimoto, Y.; Ohashi, M.; Ogoshi, S.
    6/14/2016~6/14/2016, Osaka, Japan
  • The 12th International Symposium on Organic Reactions(ISOR-12)
    "Transformation of Tetrafluoroethylene by Nickel or Copper Catalysut", Poster Presentation
    Ogoshi, S.
    4/22/2016~4/24/2016, Kyoto, Japan
  • Molecular Chirality Asia 2016
    "Enantioselective Synthesis of Benzoxasiloles: Simultaneous Generation of Carbon and Silicon Stereogenic Centers", Poster Presentation
    Kumar, R.; Hoshimoto, Y.; Ohashi, M.; Ogoshi, S.
    4/20/2016~4/22/2016, Osaka, Japan
  • 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015)
    "Transformation of tetrafluoroethylene via transition metal intermediates", Invited Lecture
    Ogoshi, S.
    12/15/2015~12/20/2015, Honolulu, Hawaii
  • 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015)
    "Nickel(0)-catalyzed transformation reactions via aza-nickelacycle intermediates", Invited Lecture
    Ogoshi, S.
    12/15/2015~12/20/2015, Honolulu, Hawaii
  • ICCEOCA-10 ARN-CEOCA-1
    "Asymmetric Synthesis of Benzoxasiloles via η2-Aldehyde Chiral Nickel(0) Complex and Reaction Path", Poster Presentation
    Ogoshi, S.
    11/2/2015~11/5/2015, Kaohsiung, Taiwan
  • XVII Organic Chemistry Conference
    "Nickel-Catalzed Transformation of Carbonyl Compounds via Hetero-Nickelacycle Intermediates", Invited Lecture
    Ogoshi, S.
    10/27/2015~10/30/2015, New Delhi, India
  • Max-Planck-Institut
    "Nickel-catalyzed Transformation of Carbonyl Compounds via Hetero-Nickelacycle Intermediates", Invited Lecture
    Ogoshi, S.
    9/3/2015~9/3/2015, Munich, Germany
  • SeleCa-Symposium
    "Transformation of Tetrafluoroethylene via Transition Metal Intermediates", Oral Presentation
    Ogoshi, S.
    9/1/2015~9/3/2015, Aachen, Germany
  • 9th French-Japanese Seminar on Fluorine
    "Transformation of Tetrafluoroethylene via Transition Metal Intermediates", Oral Presentation
    Ogoshi, S.
    8/30/2015~9/1/2015, Nice, France
  • Laboratoire de Chimie de Coordination (LCC)
    "Nickel-catalyzed Transformation of Carbonyl Compounds via Hetero-Nickelacycle Intermediates", Invited Lecture
    Ogoshi, S.
    8/27/2015~8/29/2015, Toulouse, France
  • UK Japanese Asymmetric Catalysis Symposium
    "Asymmetric Synthesis of Benzoxasiloles via η2-Aldehyde Chiral Nickel(0) Complex and Reaction Path", Invited Lecture
    Ogoshi, S.
    3/14/2015~3/15/2015, Manchester, United Kingdom

National Conference

  • 日本化学会 第99春季年会(2019)
    "Ni(0)/Chiral Phosphoramidite-Catalyzed Asymmetric Carbonylative Cycloaddition of Ene-Imines with CO", 口頭発表
    Ashida, K.; Hoshimoto, Y.; Ohashi, M.; Ogoshi, S.
    3/16/2019~3/19/2019, 神戸市
  • 日本化学会 第99春季年会(2019)
    "Hydrogen Purification Based on Catalytic Hydrogenation/Dehydrogenation of N-Heteroaromatics Mediated by Frustrated Lewis Pairs", 口頭発表
    Asada, T.; Hoshimoto, Y.; Ogoshi, S.
    3/16/2019~3/19/2019, 神戸市
  • 日本化学会 第98春季年会 (2018)
    "Phosphorylation of Carbon-Oxygen Bond with N-Phosphine Oxide-Substituted Imidazolylidenes", 口頭発表
    Asada,T.; Hazra, S.; Hoshimoto, Y.; Ogoshi, S.
    3/20/2018~3/23/2018, 船橋市