Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Yasuhiro Ohki » Japanese

Affiliation Department of Chemistry, Graduate School of Science, Nagoya University
Position Associate Professor
HP https://inorg.chem.nagoya-u.ac.jp/members/ohki/ohki-e-frame.html
Speciality organometallic chemistry, bio-inorganic chemistry, coordination chemistry
Keyword (1) Structural and functional analogues of the nitrogenase active site, (2) Synthesis of coordinatively unsaturated organometallic complexes and their application in the activation of small molecules, (3) Synthesis and reactions of metal-cluster molecules of iron-group elements
Institute Chemical society of Japan, Japan society of coordination chemistry, kinka chemical society, catalysis society of Japan, American chemical society

Abstract

Precise Formation of Dinuclear Organometallic Reaction Sites and their Application in Difficult Substrate Reductions

Achievement

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Original papers

  • "A Dinuclear Mo2H8 Complex Supported by Bulky C5H2tBu3 ligands"
    *Ohki, Y.; Ishihara, K.; Yaoi, M.; Tada, M.; Sameera, W. M. C.; Cramer, R. E.
    Chem. Commun., 2020, 56, 8035-8038
  • "Synthesis of Dinuclear Mo-Fe Hydride Complexes and Catalytic Silylation of N2"
    Ishihara, K.; Araki, Y.; Tada, M.; Takayama, T.; Sakai, Y.; *Sameera, W. M. C.; *Ohki, Y.
    Chem. Eur. J., 2020, 25, 9537-9546
  • "Synthesis, Characterization, and Application of Segphos Derivative Having Diferrocenylphosphino-Donor Moieties"
    Hu, H.; Ichiryu, H.; Seki, N.; Nakajima, K.; Ohki, Y.; *Ogasawara, M.
    Organometallics, 2020, 39, 788-792
  • "Synthesis of [Mo3S4] Clusters through Half-Sandwich Mo(V) Chlorides and Their Application as Platforms for [Mo3S4Fe] Cubes"
    *Ohki, Y.; Hara, R.; Munakata, K.; Tada, M.; Takayma, T.; Sakai, Y.; Cramer, R. E.
    Inorg. Chem., 2019, 58, 5230-5240
  • "3-[4'-(Diethylboryl)phenyl]pyridine: Exclusive Crystallization of Cyclic Tetramer"
    *Wakabayashi, S.; Sugiyama, N.; Ohki, Y.; Itoh, T.; Kitagawa, T.
    Chem. Asian J., 2019, 14, 568-573
  • "Cubane-Type [Mo3S4M] Clusters with First-Row Group 4-10 Transition-Metal Halides Supported by C5Me5 Ligands on Molybdenum"
    *Ohki, Y.; Uchida, K.; Hara, R.; Kachi, M.; Fujisawa, M.; Tada, M.; Sakai, Y.; Sameera, W. M. C.
    Chem. Eur. J., 2018, 24, 17138-17147
  • "N2 Activation on a Molybdenum-Titanium-Sulfur Cluster"
    *Ohki, Y.; Uchida, K.; Tada, M.; Cramer, R. E.; Ogura, T.; Ohta, T.
    Nat. Commun., 2018, 9, 3200
  • "Ambient Conversion of CO2 to Hydrocarbons by Biogenic and Synthetic [Fe4S4] Clusters"
    Stiebritz, M.; Hiller, C.; Sickerman, N.; Lee, C. C.; Tanifuji, K.; Ohki, Y.; *Hu, Y.
    Nat. Catal., 2018, 1, 441-451
  • "Tracing the 9th Sulfur of the Nitrogenase Cofactor via a Semi-Synthetic Approach"
    Tanifuji, K.; Lee, C. C.; Tatsumi, K.; Ohki, Y.; Hu, Y.; *Ribbe, M. W.
    Nat. Chem., 2018, 10, 568-572

Books

  • 「Recent Advances in the Chemical Synthesis of Nitrogenase Model Clusters」
    Tanifuji, K.; *Ohki, Y.
    「Struct. Bond.」, Springer , 2019, 33-61
  • 「Chemical Synthesis of an Asymmetric Mo-Fe-S Mimic of the Nitrogenase Active Site」
    *Tanifuji, K.; *Ohki, Y.
    「Methods in Molecular Biology」, Springer Science, 2019, 229-244

Review

  • 「Metal-Sulfur Compounds in N2 Reduction and Nitrogenase-Related Chemistry」 Tanifuji, K.; *Ohki, Y., Chem. Rev., 120, 5194-5251, 2020

Conference

  • 12th China-Japan Joint Symposium on Metal Cluster Compounds
    "Molybdenum-Containing Metal-Sulfur Clusters for Bio-Inspired N2 Activation", Invited Lecture
    Ohki, Y.
    10/25/2019~10/28/2019, 蘇州, 中国
  • International Congress on Pure & Applied Chemistry (ICPAC) Yangon 2019
    "Bio-inspired N2 Activation by Cubic Metal-Sulfur Clusters", Invited Lecture
    Ohki, Y.
    8/6/2019~8/9/2019, Yangon, Myanmar
  • International Workshop on New Developments and Prospects for the Future of Mössbauer Spectroscopy
    "Iron-Based Hydride Clusters: Synthesis, Characterization, and Application in the Catalytic N2 Silylation", Invited Lecture
    Ohki, Y.
    11/15/2018~11/17/2018, Nagoya, Japan
  • 2018 Nankai International Symposium on Advanced Materials
    "Synthesis of Iron-Based Hydride Clusters and Their Application in the Catalytic Silylation of N2", Invited Lecture
    Ohki, Y.
    11/12/2018~11/14/2018, Teanjin, China
  • The 43rd International Conference on Coordination Chemistry
    "C5Me5 (Cp*)-Supported Metal-Sulfur Clusters for N2 Activation ", Invited Lecture
    Ohki, Y.
    7/31/2018~8/4/2018, Sendai, Japan
  • The 15th International Symposium on Inorganic Ring Systems(IRIS-15)
    "Molecular Metal-Chalcogenides for Bio-inspired Nitrogen Activation", Invited Lecture
    Ohki, Y.
    6/24/2018~6/29/2018, Kyoto, Japan
  • The 3rd Japan-UK Joint Symposium on Coordination Chemistry
    "Cubic [Mo3S4M] Clusters with First-Row Transition Metals for Bio-inspired N2 Activation", Invited Lecture
    Ohki, Y.
    4/30/2018~5/2/2018, St. Andrews , UK

National Conference

  • 第69回錯体化学討論会 シンポジウム” Metal-ligand cooperation:New design in the development of functional organometallic complexes”
    "Organometallic Approach Toward Functional Analogues of the Nitrogenase Metallo-cofactors", 招待講演
    大木 靖弘
    9/21/2019~9/23/2019, 名古屋
  • 第65回有機金属化学討論会
    "Bio-inspired Nitrogen Activation on C5Me5 (Cp*)-Supported Metal-Sulfur Clusters", 口頭発表
    Ohki, Y.; Uchida, K.; Tada, M.; Cramer, R. E.; Sakai, Y.; Ogura, T.; Ohta, T.
    9/19/2018~9/21/2018, 京都

Award

  • 「ICPAC Yangon 2019 Lecture Award」
    受賞者:Yasuhiro Ohki
    贈呈元:the Malaysian Institute of Chemistry, and Univ. Yangon, Dept. Industrial Chemistry
    受賞日:9/2019

outreach

  • 小・中・高向け授業・実験・実習
    説明役, 名古屋大学
    名古屋, 8/10/2018~8/10/2018