Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Takuya Kurahashi » Japanese

Affiliation Department of Material Chemistry, Graduate School of Engineering, Kyoto University
Position Associate Professor
Speciality Organometallic Chemistry, Structural Organic Chemistry, Organic Synthetic Chemistry
Keyword 3d Transition-metal-catalyst, Spin-crossover, in situ X-Ray Absorption Fine Structure Analysis, Theoretical Study, Electron Spin Resonance Analysis
Institute The Kinki Chemical Society, The Chemical Society of Japan, The Society of Physical Organic Chemistry, SPring-8 Users Community, Japan Society of Coordination Chemistry, The Research Society of Innovative Integrated Molecular Materials, The Society of Synthetic Organic Chemistry, The Photofunctional Complexes Research Association, The Society of Polymer Science, Institute for Quantum Chemical Exploration, The Japan Society of Applied Physics


Development of extremely difficult substrate conversion based on modification of reaction pathway with "two-state reactivity" induced by spin-crossover


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Original papers

  • "Cu(II) Porphyrin-Catalyzed Coupling of Alkyl Tosylates and Grignard Reagents"
    Matsuoka, I.; *Kurahashi, T.; *Matsubara, S.
    Chem. Lett. , 2020, XXXX, in press
  • "Diastereoselective Synthesis of 1,3-Oxazolidines via Cationic Iron Porphyrin-catalyzed Cycloaddition of Aziridines with Aldehydes"
    Teranishi, S.; Maeda, K.; *Kurahashi, T.; *Matsubara, S.
    Org. Lett., 2019, 21, 2593–2596
  • "Cationic Cobalt Porphyrin-Catalyzed Allylation of Aldehydes with Allyltrimethylsilanes"
    Tomifuji, R.; Masuda, S; *Kurahashi, T.; *Matsubara, S.
    Org. Lett., 2019, 21, 3834–3837
  • "Asymmetric Aza-Diels-Alder Reaction with Ion-Paired-Iron Lewis Acid-Bronsted Acid Catalyst"
    Tomifuji, R.; *Kurahashi, T.; *Matsubara, S.
    Chem. Eur. J. , 2019, 25, 8987–8991
  • "Chlorotrifluoromethylation of Terminal Olefins by Atom Transfer-Type Radical Reaction Catalyzed by Cobalt Complexes"
    Maeda, K.; *Kurahashi, T.; *Matsubara, S.
    Eur. J. Org. Chem., 2019, 28, 4613–4616
  • "Nickel-Catalyzed [5+2] Cycloaddition of 10 pi-Electron Aromatic Benzothiophenes with Alkynes To Form Thermally Metastable 12 pi-Electron Nonaromatic Benzothiepines"
    Inami, T.; Takahashi, T.; *Kurahashi, T.; *Matsubara, S.
    J. Am. Chem. Soc., 2019, 141, 12541–12544
  • "Ligand-controlled Behavior of Ag(I)–π Complex as σ-Lewis Acid"
    Maeda, K.; Takahashi, T.; Tomifuji, R.; Hirao, N.; *Kurahashi, T.; *Matsubara, S.
    Chem. Lett. , 2018, 47, 532–535
  • "Nickel-catalyzed Intermolecular Carboiodination of Alkynes with Aryl Iodides"
    Takahashi, T.; Kuroda, D.; Kuwano, T.; Yoshida, Y.; *Kurahashi, T.; *Matsubara, S.
    Chem. Commun. , 2018, 54, 12750–12753
  • "FeCl3 as an Ion-Pairing Lewis Acid Catalyst. Formation of Highly Lewis Acidic FeCl2+ and Thermodynamically Stable FeCl4– To Catalyze the Aza-Diels–Alder Reaction with High Turnover Frequency"
    Tomifuji, R.; Maeda, K.; Takahashi, *T.; Kurahashi, *T.; Matsubara, S.
    Org. Lett. , 2018, 20, 7474–7477