Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Masanari Kimura » Japanese

Affiliation Division of Chemistry and Materials Science, Graduate School of Engineering, Nagasaki University
Position Professor
Contact Email
HP http://www.cms.nagasaki-u.ac.jp/lab/yuuki/index.html
Speciality Organic Synthesis, Catalytic Chemistry, Medicinal Chemistry, Structural Organic Chemistry
Keyword Phoshine-Borane、Ligands、Fine Chemicals、C–H activation
Institute Chemical Society of Japan、Society of Synthetic Organic Chemistry, American Chemical Society

Abstract

Development of Efficient Synthesis of Fine Chemicals by Using Phoshine-Borane Ligands

Achievement

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Original papers

  • "Synthesis and evaluation of topoisomerase I inhibitors possessing the 5,13-dihydro-6H-benzo[6,7]indolo[3,2-c]-quinolin-6-one scaffold"
    Fukuda, T.; Matsuo,Y.; Matsuoka, F.; Yoshioka, N.; Onodera, G.; Kimura,M.; Ishibashi, F.; Iwao, M.
    Heterocycles, 2019, 99(2), 1032-1052
  • "Assessment of DFT Methods for Transition Metals with the TMC151 Compilation of Data Sets and Comparison with Accuracies for Main-Group Chemistry"
    Chan, B.; Gill, P.M.W.; Kimura, M.
    Journal of Chemical Theory and Computation, 2019, 15(6), 3610-3622
  • "Pd-Catalyzed Dehydrogenative Oxidation of Alcohols to Functionalized Molecules"
    Mori, T.; Ishii, C.; Kimura, M.
    Organic Process Research and Development, 2019, 23(8),  1709-1717
  • "Mechanism for Three-Component Ni-Catalyzed Carbonyl–Ene Reaction for CO2 Transformation: What Practical Lessons Do We Learn from DFT Modelling?"
    *Chan, B.; Luo, Y.; *Kimura, M.
    Aust. J. Chem, 2018, 71(4), 272-278
  • "Direct Allylation of Active Methylene Compounds with Allylic Alcohols by Use of Palladium/Phosphine‐Borane Catalyst System,"
    Shimizu, A.; Hirata, G.; *Onodera, G.; *Kimura, M
    Adv. Synth. Catal., 2018, 360(10), 1954-1960
  • "Synthesis of 4,5-Disubstituted Pyrano[3,4-b]pyrrol-7(1H)-ones via Sonogashira–Hagihara Cross-coupling of N-Benzenesulfonyl-3-bromo-1H-pyrrole-2-carboxylate and Subsequent Iodine-mediated Cyclization"
    Fukuda,T.; Komure, M.; Onodera,G.; Kimura, M.; *Iwao, M.
    Heterocycles, 2018, 97(2), 916-930
  • "Ni-Catalyzed Formal Carbonyl-Ene Reaction of Terminal Alkenes via Carbon Dioxide Insertion"
    Mori, Y.; Shigeno, C.; Luo,Y.; Chan, B.; Onodera, G.; *Kimura, M.
    Synlett, 2018, 29 (6), 742-746

Books

  • 「ニッケル触媒作用を活用した炭素-炭素結合切断反応を伴う炭素骨格再構築化」」
    木村正成
    「有機合成化学協会誌」, 有機合成化学協会, 2018, 1324–1331

Conference

  • IKCOC-14
    "Cu-Catalyzed Stereoselective Formation of alpha,beta-Unsaturated Carbonyls via Alkynylborates", Oral Presentation
    Kimura, M.
    11/12/2018~11/16/2018, Kyoto, Japan
  • 28th International Conference on Organometallic Chemistry (ICOMC-2018)
    "Ni-Catalyzed Carbon Dioxide Rearrangement of Enol Aluminium Carbonates for the Synthesis of β-Ketocarboxylic Acids", Poster Presentation
    Ninokata,R.; Yamahira, T.; Masuchi, R.; Onodera,G.; Kimura, M.
    7/15/2018~7/20/2018, Florence , Italy

Award

  • 「Tarrant Distinguished Visiting Professorship of Organic Chemistry 2018, University of Florida」
    受賞者:Kimura, M.
    贈呈元: University of Florida
    受賞日:9/13/2018