Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Kazuhiro Yoshida » Japanese

Affiliation Graduate School of Science, Chiba University
Position Associate Professor
Speciality Organometallic Chemistry, Organic Synthetic Chemistry
Keyword Catalyst, Chiral Ligand, NHC, Metallocene
Institute The Chemical Society of Japan, The Society of Synthetic Organic Chemistry Japan, Kinka Chemical Society Japan

Abstract

Development of Metal Catalysts Bearing Planar Chiral Cyclic (Amino)(metallocenyl)carbene Ligands

Achievement

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Original papers

  • "Development of Planar Chiral Five-membered Cyclic (Amino)(ferrocenylene)carbene Ligand and Its Iridium Dicarbonyl Complex"
    Takagaki, W.; Yasue, R.; *Yoshida, K.
    Bull. Chem. Soc. Jpn., 2020, 93, 200-204
  • "Synthesis of [1]Benzothiopheno[2,3-b][1]benzothiophene Derivatives through Iodine-mediated Sulfuration Reaction of 1,1-Diarylethylenes"
    Sakai, S.; Sato, K.; *Yoshida, K.
    Tetrahedron Lett., 2020, 61, 151476
  • "Versatile and Enantioselective Preparation of Planar-Chiral Metallocene-Fused 4-Dialkylaminopyridines and Their Application in Asymmetric Organocatalysis"
    *Yoshida, K.; Liu, Q.; Yasue, R.; Wada, S.; Kimura, R.; Konishi, T.; *Ogasawara, M.
    ACS Catal., 2020, 10, 292-301
  • "Chiral Bicyclic NHC/Cu Complexes for Catalytic Asymmetric Borylation of α,β-Unsaturated Esters"
    Miwa, Y.; Kamimura, T.; Sato, K.; Shishido, D.; *Yoshida, K.
    J. Org. Chem., 2019, 84, 14291-14296
  • "Synthesis and Application of Planar Chiral Cyclic (Amino)(ferrocenyl)carbene Ligands Bearing FeCp* Group"
    Yasue, R.; *Yoshida, K.
    Organometallics, 2019, 38, 2211-2217

Review

  • 「N-Heterocyclic Carbene Ligands Having Planar Chiral Ferrocene Structure」 *Yoshida, K.; Yasue, R., J. Synth. Org. Chem., Jpn., 78, 28-40, 2020
  • 「Planar-Chiral Ferrocene-Based N-Heterocyclic Carbene Ligands」 *Yoshida, K.; Yasue, R., Chem. Eur. J., 24, 18575-18586, 2018

Conference

  • The 3rd Molecular Chirality Research Center Symposium
    "Planar Chiral Cyclic (Amino)(ferrocenyl)carbene as Ligand for Transition Metals", Oral Presentation
    Yoshida, K.
    3/4/2020~3/5/2020, Chiba, Japan
  • 4th International Symposium on Precisely Designed Catalysts with Customized Scaffolding
    "Synthesis and Application of Planar Chiral Cyclic(amino)(ferrocenyl)carbene Ligands Bearing FeCp*", Poster Presentation
    Yasue, R.; Yoshida, K.
    12/3/2019~12/5/2019, Nara, Japan
  • 4th International Symposium on Precisely Designed Catalysts with Customized Scaffolding
    "Versatile and Enantiolselective Preparation of Planar-Chiral Metallocene-Fused 4-Dialkylaminopyridines and Their Application in Asymmetric Organocatalysis", Poster Presentation
    Yoshida, K.; Liu, Q.; Yasue, R.; Wada, S.; Kimura, R.; Konishi, T.; Ogasawara, M.
    12/3/2019~12/5/2019, Nara, Japan
  • 20th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS 20)
    "Synthesis and Application of Planar Chiral Cyclic(amino)(ferrocenyl)carbene Bearing Cp* Group", Poster Presentation
    Yasue, R.; Yoshida, K.
    7/21/2019~7/25/2019, Heidelberg, Germany
  • The 14th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-14)
    "Development of Planar Chiral (Amino)(ferrocenyl)carbene Ligand Having Cp*Fe Moiety", Poster Presentation
    Yasue, R.; Shikata, Y.; Yoshida, K.
    11/12/2018~11/16/2018, Kyoto, Japan
  • The 14th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-14)
    "Versatile and Enantioselective Preparation of Planar-Chiral Metallocene-Fused 4-Dialkylaminopyridines and Their Application in Asymmetric Organocatalysis", Poster Presentation
    Yoshida, K.; Liu, Q.; Yasue, R.; Wada, S.; Kimura, R.; Ogasawara, M.
    11/12/2018~11/16/2018, Kyoto, Japan
  • Symposium on Molecular Chirality 2018
    "Planar Chiral Cyclic Amino(ferrocenyl)carbene as Ligand for Transition Metals", Poster Presentation
    Yasue, R.; Shikata, Y.; Yoshida, K.
    5/11/2018~5/12/2018, Chiba, Japan

National Conference

  • 第65回有機金属化学討論会
    "Fe(C<sub>5</sub>Me<sub>5</sub>)基をもつ新規面性不斉NHC配位子の開発", ポスター発表
    安江里紗、四方祐太、吉田和弘
    9/19/2018~9/21/2018, 京都
  • 第65回有機金属化学討論会
    "フェロセン縮環した面不斉環状ホスホン酸類の不斉合成", ポスター発表
    劉強、安江里紗、岡崎願之晋、吉田和弘、小笠原正道
    9/19/2018~9/21/2018, 京都

Media

  • Chem. Eur. J., カバーピクチャ
    「Planar-Chiral Ferrocene-Based N-Heterocyclic Carbene Ligands」
    Yoshida, K.; Yasue, R., 11/26/2018
    PDF File