Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Fumitoshi Shibahara » Japanese

Affiliation Department of Chemistry and Biomolecular Science, Faculty of Engineering, Gifu University
Position Associate Professor
Contact Email
Speciality Organometallic Chemistry, Coordination Chemistry, Transition-metal Catalysis, Main Group Chemistry, Organic Materials Chemistry
Keyword N-heterocyclic Carbene, Accepting Ligands, Metal Complex, Catalysis
Institute Chemical Society of Japan · The Society of Synthetic Organic Chemistry, Japan · Kinka Chemical Society


Development of New Molecular Scaffolding with Bulky and π-Accepting NHC Ligands


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Original papers

  • "Transfer Semihydrogenation of Alkynes Catalyzed by Imidazo[1,5-a]pyrid-3-ylidene–Pd complexes: Positive Effects of Electronic and Steric Features on N-Heterocyclic Carbene Ligands"
    *Shibahara, F.; Mizuno, T.; Shibata, Y.; Murai, T.
    Bull. Chem. Soc. Jpn., 2020, 93, 332-337
  • "Synthesis of Chiral Selenazolines from N‐Acyloxazolidinones via a Selenative Rearrangement of Chiral Cyclic Skeletons"
    *Shibahara, F.; Fukunaga, T.; Kubota, S.; Yoshida, A.; *Murai, T.
    Org. Lett., 2018, 20, 5826-5830
  • "Chelation-Assisted β-Selective Direct C_H Bond Arylation of 2-Thienylthioamide Catalyzed by Palladium_1,10-Phenanthroline Complexes"
    *Shibahara, F.; Asai, Y.; *Murai, T.
    Asian J. Org. Chem., 2018, 7, 1323-1326


  • 「Pd触媒芳香族C–Hカップリング反応」
    「直接的芳香族カップリング反応の設計と応用」,三浦雅博、平野康次, シーエムシー出版, 2019, 29-40


  • 「パラジウム-窒素系二座配位子錯体触媒を用いる芳香族複素環の炭素-水素結合直接官能基化反応」 *芝原文利, 有機合成化学協会誌, 77, 776-790, 2019


  • 4th International Symposium on Precisely Designed Catalysts with Customized Scaffolding
    "Substituent Effect on 1,5-Diarylimidazo[1,5-a ]pyridine-3-ylidene– Pd Complexes and Their Catalytic Applications", Poster Presentation
    Shibata, Y.; Murai, T.; Shibahara, F.
    12/3/2019~12/5/2019, 奈良, 日本
  • 4th International Symposium on Precisely Designed Catalysts with Customized Scaffolding
    "Synthesis of 5-(Arylsulfonyl)imidazo[1,5-a ]pyridine-3-ylidene and Its Catalytic Applications", Poster Presentation
    Shibahara, F.
    12/3/2019~12/4/2019, Nara, Japan
  • The 27th International Society of Heterocyclic Chemistry Congress (27th ISHC)
    "Imidazo[1,5-a]pyridine-derived NHC-type Carbenes as a Ligand for Catalysts: Characterization and Reactivity in Catalyses", Poster Presentation
    Shibahara, F.
    9/1/2019~9/6/2019, 京都, 日本
  • Τhe 14th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-14)
    "Direct C-H Bond Arylation of Thienylthioamides Catalyzed by Pd-1,10-phenanthroline Complexes", Poster Presentation
    Shibahara, F.; Asai, Y.; Murai, T.
    11/12/2018~11/16/2018, 京都, 日本
  • The 4th International Symposium on C-H Activation (ISCHA4)
    "Direct C-H Bond Arylation of Thienylthioamides by Pd/phenanthroline Complexes", Poster Presentation
    Shibahara, F.; Asai, Y.; Murai, T.
    8/30/2018~9/2/2018, 横浜, 日本
  • XXVIII International Conference on Organometallic Chemistry (ICOMC2018)
    "Synthesis of Several Transition Metal Complexes of Imidazo[1,5-<ι>a]Pyridine Carbenes and their Catalytic Applications", Oral Presentation
    Shibahara, F.; Mizuno, T.; Hattori, S.; Murai, T.
    7/15/2018~7/20/2018, Florence, Italy

National Conference

  • 日本化学会第100春季年会2020
    "イミダゾ[1,5-a]ピリジンカルベン配位子の溝呂木-Heck反応への応用", ポスター発表
    3/22/2020~3/25/2020, 千葉
  • 日本化学会第100春季年会2020
    "アニオン性配位部位を持つキラルなイミダゾ[1,5-a]ピリジンカルベン配位子の開発", ポスター発表
    3/22/2020~3/25/2020, 千葉
  • 日本化学会第100春季年会2020
    "5位にスルホニル基を持つイミダゾ[1,5-a]ピリジンカルベン配位子の合成と銅触媒によるアルキンのヒドロホウ素化反応への応用", 口頭発表
    3/22/2020~3/25/2020, 千葉
  • 日本化学会第100春季年会2020
    "Buchwald型配位子様イミダゾ[1,5-a]ピリジンカルベン配位子の電子的性質の調整と触媒反応への応用", 口頭発表
    3/22/2020~3/25/2020, 千葉
  • 第66回有機金属化学討論会
    "1,5-ジアリールイミダゾ[1,5-a]ピリジンカルベン— パラジウム錯体の置換基効果と触媒反応への応用", ポスター発表
    9/14/2019~9/16/2019, 東京
  • 第66回有機金属化学討論会
    "5-アリールスルホニルイミダゾピリジンカルベン の合成と触媒配位子としての利用", ポスター発表
    9/14/2019~9/16/2019, 東京


  • Asian Journal of Organic Chemistry, カバーピクチャ
    「Cover Feature」
    Fumitoshi Shibahara, 7/2018
    PDF File
  • ChemistryViews, その他
    「Chelation-Assisted C_H Activation」
    Fumitoshi Shibahara, 4/27/2018
    PDF File