Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Kyoko Nozaki » Japanese

Affiliation Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo
Position Professor
HP http://park.itc.u-tokyo.ac.jp/nozakilab/
Speciality Organic Synthetic Chemistry, Homogeneous Catalyst Chemistry, Organometallic Chemistry, Polymer Synthesis Chemistry
Keyword ynthetic Chemistry, Polymer Synthesis, Organic Chemistry, Homogeneous Catalyst, Renewable Resource
Institute The Chemical Society of Japan(CSJ), The Society of Synthetic Organic Chemistry, Japan(SSOCJ), The Society of Polymer Science, Japan(SPSJ), Catalysis Society of Japan(CATSJ),The Kinki Chemical Society Japan, American Chemical Society (ACS), Royal Society of Chemistry( RSC)

Abstract

◆Research Topics:
Development of Difficult Substrate Conversion Reaction toward Carbon Dioxide Utilization

Achievement

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Original papers

  • "Reductive Coupling of Carbon Dioxide and an Aldehyde Mediated by a Copper(I) Complex toward the Synthesis of α-Hydroxycarboxylic Acids"
    Masada, K.; Kusumoto, S.; Nozaki, K.
    Org. Lett. , 2020, 22, xxx
  • "Cleavage of C–C and C–O bonds in β-O-4 Linkage of Lignin Model Compound by Cyclopentadienone Group 8 and 9 Metals Complexes
    "
    S. Kusumoto, M. Kishino, K. Nozaki
    Chem. Lett., 2020, 49(5), 477–480
  • "Synthesis of Polyethylene with in-chain α,β-Unsaturated Ketone and Isolated Ketone Units by Pd-catalyzed Ring-opening Copolymerization of Cyclopropenones with Ethylene"
    Wang, X.; Seidel, F. W.; Nozaki, K.
    Angew. Chem. Int. Ed., 2019, 58, 12955–12959
  • "Reversible Polymer-Chain Modification: Ring-Opening and Closing of Polylactone"
    Moon, S.; Masada, K.; Nozaki, K.
    J. Am. Chem. Soc., 2019, 141, 10938–10942
  • "Selective Synthesis of Primary Anilines from NH3 and Cyclohexanones by Utilizing Preferential Adsorption of Styrene on the Pd Nanoparticle Surface"
    Koizumi, Y.; Jin, X.; Yatabe, T.; Miyazaki, R.; Hasegawa, J.; Nozaki, K.; Mizuno, M.; Yamaguchi, K.
    Angew. Chem. Int. Ed., 2019, 58, 10893-10897
  • "Hydrogenation of Carbon Dioxide with Organic Base by PC(II)P-Ir Catalysts"
    Takaoka, S.; Eizawa, A.; Kusumoto, S.; Nakajima, K.; *Nishibayashi, Y.; *Nozaki, K.
    Organometallics, 2018, 37, 3001-3009
  • "Branched-Selective Hydroformylation of Non-Activated Olefins Using a N-Triphos/Rh Catalyst"
    A. Phanopoulos, K. Nozaki
    ACS Catal., 2018, 8, 5799-5809
  • "Single-step construction of the anti-deoxypropionate motif from propylene: Formal total synthesis of the cuticular hydrocarbons isolated from Antitrogus parvulus"
    T. Murayama, K. Nozaki
    Angew. Chem. Int. Ed., 2018, 57, 11394–11398
  • "Selective Chain-end Functionalization of Polar Polyethylenes: Orthogonal Reactivity of Carbene and Polar Vinyl Monomers in Their Copolymerization with Ethylene"
    X. Wang, K. Nozaki
    J. Am. Chem. Soc., 2018, 140, 15635–15640
  • "Metal-Ligand Cooperative C-H Bond Formation by Cyclopentadienone Platinum Complexes"
    T. Higashi, H. Ando, S. Kusumoto, K. Nozaki
    J. Am. Chem. Soc., 2019, 141, 2247–2250
  • "Hydrogenation of Carbon Dioxide with Organic Base by PC(II)P-Ir Catalysts"
    Takaoka, S.; Eizawa, A.; Kusumoto, S.; Nakajima, K.; *Nishibayashi, Y.; *Nozaki, K.
    Organometallics, 2018, 37, 3001-3009
  • "Dehydrogenation of dimethylamine-borane catalyzed by half-sandwich Ir and Rh complexes: Mechanism and the role of Cp* non-innocence"
    S. Pal, S. Kusumoto, K. Nozaki
    Organometallics, 2018, 37, 906–914
  • "Cationic Co-Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide"
    M. Hatazawa, R. Takahashi, J. Deng, H. Houjou, K. Nozaki
    Macromolecules, 2017, 50, 7895–7900
  • "Selective Synthesis of Primary Anilines from Cyclohexanone Oximes by the Concerted Catalysis of a Mg-Al Layered Double Hydroxide Supported Pd Catalyst"
    Jin, X.; Koizumi, Y.; Yamaguchi, K.; Nozaki, K.; Mizuno, N.
    J. Am. Chem. Soc., 2017, 139, 13821-13829
  • "Formal arylation of NH3 to produce diphenylamines over supported Pd catalysts"
    Koizumi, Y.; Taniguchi, K.; Jin, X.; Yamaguchi, K.; Nozaki, K.; Mizuno, N.
    Chem. Commun., 2017, 53, 10827-10830
  • "Cp*Ir-catalyzed Acceptorless Dehydrogenation of Carbon–Carbon Single Bonds"
    H. Ando, S. Kusumoto, W.W. Wu, K. Nozaki
    Organometallics, 2017, 36, 2317–2322
  • "Copolymerisation of ethylene with polar monomers by using palladium catalysts bearing an N-heterocyclic carbene-phosphine oxide bidentate ligand"
    Tao, W.; Akita, S.; Nakano, R.; Ito, S.; Hoshimoto, Y.; Ogoshi, S.; Nozaki, K.
    Chemical Communications, 2017, 53(17), 2630-2633
  • "Reactions of 2-Methyltetrahydropyran on Silica-Supported Nickel Phosphide in Comparison with 2-Methyltetrahydrofuran"
    Bui, P. P.; Oyama, S. T.; Takagaki, A.; Carrow, B. P.; Nozaki, K.
    ACS Catal., 2016, 6(7), 4549–4558
  • "Facile Styrene Formation from Ethylene and a Phenylplatinum(II) Complex Leading to an Observable Platinum(II) Hydride"
    Pal, S.; Kusumoto, S.; Nozaki, K.
    Organometallics, 2017, 36(3), 502–505
  • "Ni-Mg-Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromatization"
    Jin, X.; Taniguchi, K.; Yamaguchi, K.; Nozaki, K.; Mizuno, N.
    Chem. Commun., 2017, 53, in press
  • "Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold–palladium bimetallic nanoparticles"
    Taniguchi, K.; Jin, X.; Yamaguchi, K.; Nozaki, K.; Mizuno, N.
    Chem. Sci., 2017, 8, 2131-2142
  • "Copolymerisation of Ethylene with Polar Monomers by Palladium Catalysts Bearing an N-Heterocyclic Carbene–Phosphine Oxide Bidentate Ligand"
    Tao, W.; Akita, S.; Nakano, R.; Ito, S.; Hoshimoto, Y.; Ogoshi, S.; Nozaki, K.
    Chem. Commun., 2017, 53, 2630–2633
  • "Ni–Mg–Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromatization"
    Jin, X.; Taniguchi, K.; Yamaguchi, K.; Nozaki, K.; Mizuno, N.
    Chem. Commun., 2017, 53, 5267–5270.
  • "Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold–palladium bimetallic nanoparticles"
    Taniguchi, K.; Jin, X.; Yamaguchi, K.; Nozaki,K.; Mizuno, N.
    Chem. Sci., 2017, 8, 2131-2142
  • "In Situ Generation of Salen/Co(III) Complexes for Copolymerization of Propylene Oxide and CO2"
    Hatazawa, M.; Nakabayashi, K.; Ohkoshi, S.; Nozaki, K.
    Chem. Eur. J., 2016, 22, 13677-13681
  • "Development of Highly Active Ir­PNP Catalysts for Hydrogenation of Carbon Dioxide with Organic Bases"
    Aoki, W.; Wattanavinin, N.; Kusumoto, S.; Nozaki, K.
    Bull. Chem. Soc. Jpn., 2016, 89(1), 113-124
  • "Pyrazole Supported Zinc(II) Benzoates as Catalysts for the Ring Opening Copolymerization of Cyclohexene Oxide and Carbon Dioxide"
    Lephoto, M. L.; Nakano, K.; Appavoo, D.; Owaga, B. O.; Nozaki, K.; Darkwa J.
    Catalysts, 2016, 6(1), 17

Review

  • 「Cleavage of Si–H, B–H and C–H Bonds by Metal-Ligand Cooperation」 T. Higashi, S. Kusumoto, K. Nozaki, Chem. Rev., 119, 10393-10402, 18, 2019

Conference

  • The 2nd Japan Germany Singapore Trilateral Symposium on Precision Synthesis and Catalysis
    "Toward Efficient Utilization of Renewable Resources: Ligand Contribution to Late Transition Metal Mediated Reactions", Invited Lecture
    Nozaki, K.
    12/2/2019~12/4/2019, Nara, Japan
  • GDCh Science Forum Chemistry (WiFo 2019)
    "Homogeneous Catalysis for Today and Tomorrow", Plenary Lecture
    Nozaki, K.
    9/15/2019~9/19/2019, Aachen, Germany
  • Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS) of Polymers
    "Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS) of Polymers", Plenary Lecture
    Nozaki, K.
    7/21/2019~7/25/2019, Heidelberg, Germany
  • 47th IUPAC World Chemistry Congress
    "Homogeneous Catalysis for Organic Synthesis and Polymer Synthesis", Plenary Lecture
    Nozaki, K.
    7/7/2019~7/12/2019, Paris, France
  • 43rd International Conference on Coordination Chemistry
    "Synthesis of PC(II)P-Ir Complex and Application to Hydrogenation of CO2", Poster Presentation
    Satoko Takaoka, Aya Eizawa, Shuhei Kusumoto, Kazunari Nakajima, Yoshiaki Nishibayashi, Kyoko Nozaki
    7/30/2018~8/4/2018, Sendai , Japan
  • 28th International Conference on Organometallic Chemistry
    "Development of stereospecific propylene oligomerization toward single-step synthesis of deoxypropionate motif", 口頭発表
    Toshiki Murayama, Yusuke Ota, Kyoko Nozaki
    07/15/2018~07/20/2018, Florence, Italy
  • 21st International Symposium on Homogeneous Catalysis
    "Iso-Selective Hydroformylation of Non-Activated Alkenes", 口頭発表
    Andreas Phanopoulos, Kyoko Nozaki
    07/08/2018~07/13/2018, Amsterdam, The Netherlands
  • Symposium des 50 ans du LHFA
    "Unsymmterical bidentate ligand for homogeneous catalysis", Plenary Lecture
    Kyoko Nozaki
    9/20/2017~9/20/2017, Toulose, France
  • 2017 KJF International Conference on Organic Materials for Electronics and Photonics
    "Electron Transport of Solid-State Single Molecular Device with Quinoidal Fused Oligosilole Derivative", Poster Presentation
    Seung Joo Lee, Shuhei Urayama, Yasuo Azuma, Tomohiro Tsuda, Ryo Takano, Ryo Shintani, Kyoko Nozaki, Yutaka Majima
    8/30/2017~9/2/2017, Gwangju Institute of Science and Technology, Gwangju, Korea
  • 17th International Symposium on Novel Aromatics
    "Synthesis, Structure, and Properties of Azapentabenzocorannulenes", Poster Presentation
    Shingo Ito, Taro Nagano, Yuki Tokimaru, Kyoko Nozaki
    7/23/2017~7/28/2017, Stony Brook University, Stony Brook, New York, USA
  • 19th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    "Asymmetric Synthesis of Silicon-Stereogenic 5,10-Dihydrophenazasilines via Enantioselective 1,5-Palladium Migration", Poster Presentation
    Yosuke Sato, Chihiro Takagi, Ryo Shintani, Kyoko Nozaki
    6/25/2017~6/29/2017, International Convention Center JEJU (ICC JEJU), Jeju, Korea
  • U. Montreal Lecture Series
    "Development of New Catalytic Reactions toward Utilization of Renewable Resources", Invited Lecture
    Nozaki, K.
    3/16/2017~3/16/2017, Montreal, Quebec, Canada
  • LAVAL University Lecture Series
    "Development of New Catalytic Reactions toward Utilization of Renewable Resources", Invited Lecture
    Nozaki, K.
    3/15/2017~3/15/2017, Montreal, Quebec, Canada
  • McGill University Lecture Series
    "Development of New Catalytic Reactions toward Utilization of Renewable Resources", Invited Lecture
    Nozaki, K.
    3/14/2017~3/14/2017, Montreal, Quebec, Canada
  • International Symposium on C-O Activation (ISCO-2016)
    "Direct and Selective Hydrogenolysis of Arenols and Aryl Methyl Ethers", Invited Lecture
    Nozaki, K.
    10/27/2016~10/27/2016, Hyogo, Japan
  • 24th Solvay Conference on Chemistry Catalysis in Chemistry and Biology
    "Development of New Catalytic Reactions toward Utilization of Renewable Resources", Invited Lecture
    Nozaki, K.
    10/19/2016~10/19/2016, Brussels, Belgium
  • Merck-Pfister Lecturer in Organic Chemistry MIT
    "Development of New Catalysts toward Utilization of Renewable Resources", Invited Lecture
    Nozaki, K.
    9/9/2016~9/9/2016, Massachusetts, Japan
  • Merck-Pfister Lecturer in Organic Chemistry MIT
    "Organic Synthesis of Polymers", Invited Lecture
    Nozaki, K.
    9/8/2016~9/8/2016, Massachusetts, USA
  • 20th International Symposium on Homogeneous Catalysis (ISHCXX)
    "The Retro-Hydroformylation Reaction", Poster Presentation
    Tatsuki, T.; Kusumoto, S.; Nozaki, K.
    7/10/2016~7/15/2016, Kyoto, Japan
  • National Sun Yat-sen University Symposium
    "Development of New Catalytic Reactions toward Utilization of Renewable Resources", Invited Lecture
    Nozaki, K.
    6/1/2016~6/1/2016, Kaohsiung, Taiwan
  • Mini-Symposium on Organic Synthesis, Organometallics and Elemento-Organic Chemistry
    "Development of New Catalytic Reactions toward Utilization of Renewable Resources", Invited Lecture
    Nozaki, K.
    5/30/2016~5/30/2016, Taipei, Taiwan
  • Carbon Dioxide Catalysis Conference 2016 (ZING Conference)
    "Utilization of Carbon Dioxide as a Carbon Resource in Bulk Chemicals and in Polymeric Materials", Invited Lecture
    Nozaki, K.
    4/21/2016~4/21/2016, Algarve, Portugal
  • SeleCa Workshop on Precision Polymerization Catalysis
    "Catalyst Development for Utilization of Renewable Resources", Invited Lecture
    Nozaki, K.
    4/18/2016~4/18/2016, Aachen, Germany
  • Challenges in Organic Chemistry
    "Development of New Catalysts toward Utilization of Renewable Resources", Plenary Lecture
    Nozaki, K.
    3/21/2016~3/21/2016, アーバイン, アメリカ合衆国
  • The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015)
    "Carbon dioxide as a renewable C1 feedstock for polymer synthesis", Invited Lecture
    Nozaki, K.
    12/15/2015~12/20/2015, ホノルル, アメリカ合衆国
  • IUPAC-2015
    "Development of New Catalytic Reactions toward Utilization of Renewable Resources", Invited Lecture
    Nozaki, K.
    8/11/2015~8/11/2015, 釜山, 韓国
  • Gordon Research Conference-New Challenges and Opportunities for Organometallic Chemistry-
    "Development of New Catalytic Reactions Toward Utilization of Renewable Resources", Invited Lecture
    Nozaki, K.
    7/12/2015~7/12/2015, Newport, アメリカ合衆国
  • 7th International Conference on Green and Sustainable Chemistry
    "Development of New Catalytic Reactions toward Utilization of Renewable Resources", Invited Lecture
    Nozaki, K.
    7/7/2015~7/7/2015, 東京, 日本

National Conference

  • 第97春季年会
    "イリジウム触媒を用いた炭素-酸素結合の選択的加水素分解", 口頭発表
    Nishiuchi, T.; Kusumoto, S.; Nozaki, K.
    3/16/2017~3/19/2017, 神奈川県横浜市
  • 第12回バイオマス科学会議
    "イリジウム触媒を用いた炭素–酸素結合の選択的加水素分解反応", 口頭発表
    Kusumoto, S.; Nishiuchi, T.; Nozaki, K.
    1/18/2017~1/20/2017, 東京都文京区
  • 2016年度高分子講演会 金属錯体の特異な反応性を用いた新規高分子(超分子)の設計・合成と機能
    "高分子の有機合成", 招待講演
    Nozaki, K.
    11/15/2016~11/15/2016, 広島県東広島市
  • 錯体化学会第66回討論会
    "イリジウム錯体を用いたカルボニル化合物のアルファ・ベータ不飽和化反応の開発", 口頭発表
    Ando, H.; Kusumoto, S.; Nozaki, K.
    9/10/2016~9/12/2016, 福岡県福岡市
  • 第65回高分子学会年次大会
    "In situ Generation of Salen/Co(III) Complexes for Copolymerization of Propylene Oxide and CO2", 口頭発表
    Hatazawa, M.; Nozaki, K.
    5/25/2016~5/27/2016, 兵庫県神戸市

Award

  • 「The Chemical Society of Japan Award」
    受賞者:Nozaki, K.
    贈呈元:The Chemical Society of Japan
    受賞日:3/23/2020
  • 「Kuggie Vallee Distiguished Lecturer」
    受賞者:Nozaki, K.
    贈呈元:Vallee Foundation
    受賞日:10/21/2019
  • 「Earl Muetterties Lectureship Award」
    受賞者:野崎京子
    贈呈元:University of California, Berkeley
    受賞日:9/20/2019
  • 「August Wilhelm von Hofmann Lecture Award」
    受賞者:野崎京子
    贈呈元:German Chemical Society
    受賞日:9/15/2019
  • 「The Karl-Ziegler-Guest Professorship」
    受賞者:野崎京子
    贈呈元:Max-Planck-Institut für Kohlenforschung, Mülheim
    受賞日:10/29/2018
  • 「LAC L. M. Venanzi Distinguished Lecturer 2018」
    受賞者:野崎京子
    贈呈元:ETH Zürich
    受賞日:3/28/2018
  • 「2015 Arthur K. Doolittle Award」
    受賞者:Nozaki, K.
    贈呈元:Amercian Chemical Society
    受賞日:3/16/2016
  • 「The 30th W. S. Johnson Lecturer」
    受賞者:野崎京子
    贈呈元:Dept. of Chem. Stanford University
    受賞日:10/9/2015

Media

  • Organometallics, カバーピクチャ
    Takaoka, S.; Eizawa, A.; Kusumoto, S.; Nakajima, K.; *Nishibayashi, Y.; *Nozaki, K., 7/30/2018
    PDF File
  • 日経産業新聞, 新聞
    「「CO2から樹脂合成 高効率の触媒開発 東大・岡山大 排ガス有効利用へ」 」
    野崎京子, 6/15/2018
  • J. Am. Chem. Soc., カバーピクチャ
    「Selective Synthesis of Primary Anilines from Cyclohexanone Oximes by the Concerted Catalysis of a Mg-Al Layered Double Hydroxide Supported Pd Catalyst」
    Jin, X.; Koizumi, Y.; Yamaguchi, K.; Nozaki, K.; Mizuno, N. , 10/4/2017
    PDF File
  • Chem. Commun., カバーピクチャ
    「A Ni-Mg-Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromatization」
    Jin, X.; Taniguchi, K.; Yamaguchi, K.; Nozaki, K.; Mizuno, N., 5/2017
    PDF File