Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Yoshiaki Nakao » Japanese

Affiliation Graduate School of Engineering, Kyoto University
Position Professor
HP http://www.npc05.kuic.kyoto-u.ac.jp/npc05/?lang=en
Speciality Organic Synthesis, Organometallic Chemistry
Keyword C-H activation, C-C activation, C-O activation, C-N activation
Institute The Chemical Society of Japan, The Kinki Chemical Society Japan, The Society of Synthetic Organic Chemistry Japan, The Society of Silicon Chemistry Japan, American Chemical Society

Abstract

◆Research Topics:
Studies on Extremely Difficult Substrate Conversion Reactions through Activation of Unreactive Bonds

Achievement

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Original papers

  • "Pd/NHC-catalyzed cross-coupling reactions of nitroarenes"
    Kashihara, M.; Zhong, R.-L.; Semba, K.; Sakaki, S.; *Nakao, Y.
    Chem. Commun., 2019, 55, 9291-9294
  • "Synthesis of N-Heterocyclic Carbene Ligands for Site-Selective C–H Alkylation by Cooperative Nickel/Aluminum Catalysis"
    Okumura, S.; Ebara, T.; Semba, K.; *Nakao, Y.
    Heterocycles, 2019, 99, 1128-1144
  • "meta-Selective C−H Borylation of Benzamides and Pyridines by an Iridium−Lewis Acid Bifunctional Catalyst"
    Yang, L.; Uemura, N.; *Nakao, Y.
    J. Am. Chem. Soc., 2019, 141, 7972-7979
  • "Aluminum‐Mediated C6‐Selective C−H Alkylation of 2‐Carbamoylbenzofuran by Nickel Catalysis"
    Okumura, S.; *Nakao, Y.
    Asian J. Org. Chem., 2018, 7, 1355
  • "Reductive Denitration of Nitroarenes"
    Kashihara, M.; Yadav, R. M.; *Nakao, Y.
    Org. Lett., 2018, 20, 1655
  • "Site-Selective Linear Alkylation of Anilides by Cooperative Nickel/Aluminum Catalysis"
    Okumura, S.; Komine, T.; Shigeki, E.; Semba, K.; *Nakao, Y.
    Angew. Chem. Int. Ed., 2018, 57(4), 929
  • "Buchwald–Hartwig Amination of Nitroarenes"
    Inoue, F.; Kashihara, M.; Yadav, R. M.; *Nakao, Y.
    Angew. Chem. Int. Ed., 2017, 56(43), 13307
  • "The Suzuki−Miyaura Coupling of Nitroarenes"
    Yadav, R. M.; Nagaoka, M.; Kashihara, M.; Zhong, R.-L.; Miyazaki, T.; *Sakaki, S.; *Nakao, Y.
    J. Am. Chem. Soc, 2017, 139(28), 9423
  • "C3-Selective Alkenylation of N-Acylindoles with Unactivated Internal Alkynes by Cooperative Nickel/Aluminium Catalysis"
    Inoue, F.; Saito, T.; Semba, K.; *Nakao, Y.
    Chem. Commun., 2017, 53(32), 4497
  • "para-Selective Alkylation of Benzamides and Aromatic Ketones by Cooperative Nickel/Aluminum Catalysis"
    Okumura, S.; Tang, S.; Saito, T.; Semba, K.; *Sakaki, S.; *Nakao, Y.
    J. Am. Chem. Soc., 2016, 138(44), 14699
  • "para-Selective Alkylation of Sulfonylarenes by Cooperative Nickel/Aluminum Catalysis"
    Okumura, S.; *Nakao, Y.
    Org. Lett., 2017, 19(3), 584
  • "para-Selective C-H Borylation of (Hetero)Arenes by Cooperative Iridium/Aluminum Catalysis"
    Yang, L.; Semba, K.; *Nakao, Y.
    Angew. Chem. Int. Ed., 2017, 56(17), 4853
  • "Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel-N-Heterocyclic Carbene System"
    Schramm, Y.; Takeuchi, M.; Semba, K.; *Nakao, Y.; *Hartwig, J. F.
    J. Am. Chem. Soc., 2015, 137(38), 12215
  • "Selective Hydrogenolysis of Arenols with Hydrosilanes by Nickel Catalysis"
    Ohgi, A.; *Nakao, Y.
    Chem. Lett., 2016, 45(1), 45

Books

  • 「Hydroarylation」
    Nakao, Y.
    「Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis Vol. 1」,Nolan, S. P., Cazin, C. S. J., Georg Thieme Verlag KG, 2017

Conference

  • The 2nd Japanese-Sino Symposium on Catalysis for Precision Synthesis
    "Catalytic C–X Functionalization at Al–Rh Bonds", Invited Lecture
    Nakao, Y.
    12/6/2019~12/7/2019, Kyoto, Japan
  • The 4th International Symposium on Precisely Designed Catalysts with Customized Scaffolding
    "Cross-coupling Reactions of Nitroarenes", Oral Presentation
    Nakao, Y.
    12/3/2019~12/5/2019, Nara, Japan
  • Israel–Japan Conference “Molecular Catalysis in the Service of Society”
    "Catalytic C–X Functionalization at Al–Rh Bonds", Invited Lecture
    Nakao, Y.
    11/3/2019~11/5/2019, Haifa, Israel
  • Shanghai Institute of Organic Chemistry
    "Cross-Coupling Reactions by Cooperative Metal Catalysis", Invited Lecture
    Nakao, Y.
    10/14/2019~10/14/2019, Shanghai, China
  • The Chinese University of Hong Kong (ACP Lectureship)
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    10/11/2019~10/11/2019, Hong Kong, China
  • The 1st International Symposium on Molecular Recognition and Synthesis
    "C–H Functionalization by Cooperative Metal Catalysis", Invited Lecture
    Nakao, Y.
    10/11/2019~10/13/2019, Shanghai, China
  • The University of Hong Kong (ACP Lectureship)
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    10/10/2019~10/10/2019, Hong Kong, China
  • The Hong Kong Polytechnic University (ACP Lectureship)
    "Cooperative Metal Catalysis for Efficient Organic Synthesis ", Invited Lecture
    Nakao, Y.
    10/9/2019~10/9/2019, Hong Kong, China
  • The 14th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-14)
    "Site- and Enantioselective C–H Borylation of Cyclic Amines by Cooperative Iridium/Aluminum Catalysis", Poster Presentation
    Nakao, Y.
    9/26/2019~9/29/2019, Niseko, Japan
  • The 2nd JGP Chem & ChemEn International Workshop: Sustainability-Oriented Organic Synthesis
    "C–H Functionalization by Cooperative Metal Catalysis", Invited Lecture
    Nakao, Y.
    9/9/2019~9/10/2019, Kyoto, Japan
  • The 47th Naito Conference: C–H Bond Activation and Transformation
    "C–H Functionalization of Heterocycles by Cooperative Catalysis", Invited Lecture
    Nakao, Y.
    7/2/2019~7/5/2019, Sapporo, Japan
  • Gordon Research Conference: Heterocyclic Compounds
    "C–H Functionalization of Heterocycles by Cooperative Catalysis", Invited Lecture
    Nakao, Y.
    6/16/2019~6/21/2019, Newport, USA
  • Technion - Israel Institute of Technology (David Ginsburg Memorial Lectureship)
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    3/28/2019~3/28/2019, Haifa, Israel
  • Ben Gurion University of the Negev
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    3/27/2019~3/27/2019, Beer-Sheva, Israel
  • Hebrew University of Jerusalem
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    3/26/2019~3/26/2019, Jerusalem, Israel
  • Tel Aviv University
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    3/24/2019~3/24/2019, Tel Aviv, Israel
  • The 8th Spanish-Portuguese-Japanese Organic Chemistry Symposium (8th SPJ-OCS)
    "C–H Functionalization by Cooperative Metal Catalysis", Invited Lecture
    Nakao, Y.
    11/9/2018~11/9/2018, Kyoto, Japan
  • The 13th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-13)/The 4th Advanced Research Network- on Cutting-Edge Organic Chemistry in Asia (ARNCEOCA-4)
    "C2-Selective Alkylation of Pyridine by a Rhodium Complex Bearing an X-type Aluminum Ligand", Poster Presentation
    Hara, N.; Nakao, Y.
    11/1/2018~11/4/2018, Bangkok, Thailand
  • Central China Normal University (ACP Lectureship)
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    10/23/2018~10/23/2018, Wuhan, China
  • Chem-Reaxys Symposium (ACP Lectureship)
    "Cooperative Metal Catalysis for C–H Functionalization", Invited Lecture
    Nakao, Y.
    10/22/2018~10/22/2018, Wuhan, China
  • Korea University (ACP Lectureship)
    "Cooperative Metal Catalysis for Cross-coupling Reactions", Invited Lecture
    Nakao, Y.
    9/13/2018~9/13/2018, Seoul, Korea
  • Chonnam National University (ACP Lectureship)
    "Cooperative Metal Catalysis for Cross-coupling Reactions", Invited Lecture
    Nakao, Y.
    9/12/2018~9/12/2018, Gwangju, Korea
  • Pusan National University (ACP Lectureship)
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    9/11/2018~9/11/2018, Pusan, Korea
  • JGP Chem & ChemEn International Workshop: Sustainability-Oriented Organic Synthesis
    "C–H Functionalization by Cooperative Metal Catalysis", Invited Lecture
    Nakao, Y.
    9/3/2018~9/4/2018, Kyoto, Japan
  • Università di Bologna
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    7/2/2018~7/2/2018, Bologna, Italy
  • Nanjing University
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    6/11/2018~6/11/2018, Nanjing, China
  • The 1st Sino-Japanese Symposium on Catalysis for Precision Synthesis
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    5/27/2018~5/30/2018, Shanghai, China
  • IRCCS-JST CREST Joint Symposium
    "para-Selective Alkylation of Benzamides by Cooperative Nickel/Aluminum Catalysis", Oral Presentation
    Nakao, Y.
    1/24/2018~1/26/2018, Fukuoka, Japan
  • 1st Singapore Japan Germany Trilateral Symposium on Precision Synthesis&Catalysis
    "C–H Functionalization by Cooperative Metal Catalysis", Invited Lecture
    Nakao, Y.
    11/20/2017~11/22/2017, Singapore, Singapore
  • The 12th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-12)/The 3rd Advanced Research Network- on Cutting-Edge Organic Chemistry in Asia (ARNCEOCA-3)
    "Reductive Denitration of Nitroarenes", Poster Presentation
    Nakao, Y.
    11/2/2017~11/5/2017, Xi'an, China
  • Symposium on Nickel and Related Chemistry
    "Nickel Catalysis for Hydroarylation and Related Reactions", Invited Lecture
    Nakao, Y.
    10/8/2017~10/10/2017, Shanghai, China
  • 1st International Symposium on Catalysis for Sustainable Chemical Synthesis Joint Symposium of FRIAS/Nagoya IAR
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    9/25/2017~9/26/2017, Freiburg, Germany
  • Nordic/Kyoto OMCOS 2017
    "C–H Functionalization by Cooperative Catalysis", Invited Lecture
    Nakao, Y.
    6/23/2017~6/24/2017, Kyoto, Japan
  • SUS Tech Chemical Sciences Lectureship
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    5/4/2017~5/4/2017, Shenzhen, China
  • 9th Asian-European Symposium on Metal-Mediated Efficient Organic Synthesis
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    9/4/2016~9/7/2016, Stockholm, Sweden
  • The 3rd International Conference on Organometallics and Catalysis
    "Cooperative Metal Catalysis for Efficient Organic Synthesis", Invited Lecture
    Nakao, Y.
    8/28/2016~8/30/2016, Seoul, Korea
  • Pacifichem 2015
    "C-C Bond Forming Reactions by Cooperative Metal Catalysis", Invited Lecture
    Nakao, Y.
    12/15/2015~12/20/2015, Honolulu, USA
  • 6th International Collaborative and Cooperative Chemistry Symposium
    "C-C Bond Forming Reactions by Cooperative Metal Catalysis", Invited Lecture
    Nakao, Y.
    11/16/2015~11/17/2015, Seoul, Korea
  • 16th Tetrahedron Symposium Asia Edition
    "C-C Bond Forming Reactions by Cooperative Metal Catalysis", Invited Lecture
    Nakao, Y.
    11/11/2015~11/11/2015, Shanghai, China
  • Kick-off Symposium on Advanced Research Network for Cutting-Edge Organic Chemistry in Asia
    "C-C Bond Forming Reactions by Cooperative Metal Catalysis", Invited Lecture
    Nakao, Y.
    8/26/2015~8/26/2015, Sendai, Japan
  • 45th World Chemistry Congress
    "C-C Bond Forming Reactions by Cooperative Metal Catalysis", Invited Lecture
    Nakao, Y.
    8/9/2015~8/14/2015, Busan, Korea
  • 16th Tetrahedron Symposium
    "C-C Bond Forming Reactions by Cooperative Metal Catalysis", Invited Lecture
    Nakao, Y.
    6/16/2015~6/19/2015, Berlin, Germany

Award

  • 「David Ginsburg Memorial Lectureship」
    受賞者:Nakao, Y.
    贈呈元:Israel Institute of Technology
    受賞日:11/22/2017
  • 「Asian Core Program Lectureship Award 2017 (Korea)」
    受賞者:Nakao, Y.
    贈呈元:Advanced Research Network for Asian Cutting-Edge Organic Chemistry
    受賞日:11/5/2017
  • 「Mukaiyama Award 2017」
    受賞者:Nakao, Y.
    贈呈元:The Society of Synthetic Organic Chemistry, Japan
    受賞日:9/12/2017
  • 「SUSTech Chemical Sciences Lectureship」
    受賞者:Yoshiaki Nakao
    贈呈元:Southern University of Science and Technology
    受賞日:5/4/2017
  • 「Asian Core Program Lectureship Award 2015 (Hong Kong)」
    受賞者:中尾佳亮
    贈呈元:ACP organizing committee
    受賞日:11/5/2015
  • 「Tetrahedron Young Investigator Award」
    受賞者:中尾佳亮
    贈呈元:Elsevier
    受賞日:6/17/2015

conference _management

  • 「The 2nd Japanese-Sino Symposium on Catalysis for Precision Synthesis」
    国際会議, Chairperson, 12/6/2019~12/7/2019, Kyoto, Japan