Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Junji Ichikawa » Japanese

Affiliation Division of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba
Position Professor
Contact Email
HP http://www.chem.tsukuba.ac.jp/junji/index_english.html
Speciality synthetic organic chemistry, organofluorine chemistry, organometallic chemistry
Keyword chemical transformation, fluorine, metal catalyst, bond activation
Institute The Chemical Society of Japan. The Society of Synthetic Organic Chemistry, Japan. American Chemical Society. International Society of Heterocyclic Chemistry. The Society of Fluorine Chemistry, Japan. University-Industry Cooperative Research Committee, Fluorine Chemistry 155.

Abstract

Carbon-fluorine bond activation via fluorine eliminations

Achievement

Printer friendly view

Original papers

  • "Synthesis of Ring-Fluorinated Thiophene Derivatives Based on Single C–F Bond Activation of CF3-Cyclopropanes: Sulfanylation and 5-endo-trig Cyclization"
    Fuchibe, K.; Fushihara, K.;*Ichikawa, J.
    Org. Lett. , 2020, 22, 2201–2205
  • "Fluorinated Phenanthrenes as Aryne Precursors: PAH Synthesis Based on Domino Ring Assembly Using 1,1‐Difluoroallenes"
    Fuchibe, K.; Abe, M.; Idate, H.; *Ichikawa, J.
    Chem. Asian J. , 2020, , in press.
  • "Gold-Catalyzed Electrophilic Activation of 1,1-Difluoroallenes: α- and γ-Selective addition of Heteroatom Nucleophiles"
    Fuchibe, K.; Abe, M.; Sasaki, M.; *Ichikawa, J.
    J. Fluorine Chem., 2020, , in press
  • "Nickel-catalyzed [4 + 2] Cycloaddition of Styrenes with Arynes via 1:1 Cross-coupling: Synthesis of 9,10-Dihydrophenanthrenes"
    Kubo, T.; Fujita, T.; *Ichikawa, J.
    Chem. Lett. , 2020, 49, 264–266
  • "Methylarene-Based PAH Synthesis via Domino Cyclization of 1,1-Difluoro-1-alkenes"
    Fuchibe, K.; Takao, G.; Takahashi, H.; Ijima, S.; *Ichikawa, J.
    Bull. Chem. Soc. Jpn. , 2019, 92, 2019–2029
  • "Brønsted Acid-Catalysed Hydroarylation of Unactivated Alkynes in Fluoroalcohol–Hydrocarbon Biphasic System: Construction of Phenanthrene Frameworks"
    Takahashi, I.; Fujita, T.; Shoji, N.; *Ichikawa, J.
    Chem. Commun., 2019, 55, 9267-9270
  • "Construction of Pinpoint-Fluorinated Benzothiophene Frameworks Using Palladium-Catalyzed Cyclization of o-(Fluorovinyl)phenyl-substituted Thiophenes"
    Fuchibe, K.; Tsuda, N.; Shigeno, K.; *Ichikawa, J.
    Heterocycles , 2019, 99, 1196-1216
  • "Synthesis of 3‐(Trifluoromethyl)indoles via Oxidative Cyclization of o‐Sulfonamido‐α‐(trifluoromethyl)styrenes"
    Fujita, T.; Ide, K.; Jankins, T. C.; Nojima, T.; *Ichikawa, J.
    Asian J. Org. Chem., 2019, 8, 637-640
  • "Nucleophilic 5-endo-trig cyclization of 2-(trifluoromethyl)allylic metal enolates and enamides: Synthesis of tetrahydrofurans and pyrrolidines bearing exo-difluoromethylene units"
    Fujita, T.; Hattori, M.; Matsuda, M.; Morioka, R.; Tanner, C. J.; Ikeda, M.; *Ichikawa, J.
    Tetrahedron, 2019, 75, 36
  • "Single C–F Bond Activation of the CF3 Group with a Lewis Acid: CF3-Cyclopropanes as Versatile 4,4-Difluorohomoallylating Agents"
    Fuchibe, K.; Oki, R.; Hatta, H.; *Ichikawa, J.
    Chem. Eur. J. , 2018, 24, 17932
  • "sp3Carbon–Fluorine Bond Activation in 2,2-Difluorohomoallylic Alcohols via Nucleophilic 5-endo-trig Cyclisation: Synthesis of 3-Fluorinated Furan Derivatives"
    Fujita, T.; Morioka, R.; Arita, T.; *Ichikawa, J.
    Chem. Commun. , 2018, 54, 12938
  • "Flash generation and borylation of 1-(trifluoromethyl)vinyllithium toward synthesis of α-(trifluoromethyl)styrenes"
    Fujita, T.; Knnno, N.; Watabe, Y.; Ichitsuka, T.; Nagaki, A.; Yoshida, J.; Ichikawa, J.
    J. Fluorine Chem. , 2018, 207, 72-76
  • "Regioselective Syntheses of Fluorinated Cyclopentanone Derivatives: Ring Construction Strategy Using Transition-Metal– Difluorocarbene Complexes and Free Difluorocarbene"
    Fuchibe, K.; Takayama, R.; Aono, T.; Hu, J.; Hidano, T.; Sasagawa, H.; Fujiwara, M.; Miyazaki, S.; Nadano, R.; Ichikawa, J.
    Synthesis , 2018, 50, 514-528
  • "Metal-free synthesis of α,α-difluorocyclopentanone derivatives via regioselective difluorocyclopropanation/VCP rearrangement of silyl dienol ethers"
    Fuchibe, K.; Takayama, R.; Ichikawa, J.
    ARKIVOC, 2018, , 72-80
  • "Ring-Size-Selective Construction of Fluorine-Containing Carbocycles via Intramolecular Iodoarylation of 1,1-Difluoro-1-alkenes"
    Fujita, T.; Kinoshita, R.; Takanohashi, T.; Suzuki, N.; Ichikawa, J.
    Beilstein J. Org. Chem., 2017, 13, 2682-2689
  • "Pinpoint-fluorinated Polycyclic Aromatic Hydrocarbons (F-PAHs): Syntheses of Difluorinated Subfamily and Their Properties"
    Fuchibe, K.; Shigeno, K.; Zhao, N.; Aihara, H.; Akisaka, R.; Morikawa, T.; Fujita, T.; Yamakawa, K.; Shimada, T.; Ichikawa, J.
    J. Fluorine Chem. , 2017, 203, 173-184
  • "Synthesis of Sulfanylated Difluoroalkenes: Electrophilic Difluoromethylidenation of Dithioesters with Difluorocarbene"
    Takayama, R.; Yamada, A.; Fuchibe, K.; Ichikawa, J.
    Org. Lett., 2017, 19, 5050-5053
  • "Synthesis of Pinpoint-Fluorinated Polycyclic Aromatic Hydrocarbons: Benzene Ring Extension Cycle Involving Microwave-Assisted SNAr Reaction"
    Fuchibe, K.; Imaoka, H.; Ichikawa, J.
    Chemistry - An Asian Journal, 2017, 12, 2359-2363 [cover picture]
  • "Synthetic Methods for Ring-Fluorinated Pyrrole Derivatives"
    Fujita, T.; Ichikawa, J.
    Heterocycles , 2017, 95, 694-714
  • "Nickel-Catalyzed Hydroalkenylation of Alkynes via C–F Bond Activation: Synthesis of 2-Fluoro-1,3-dienes"
    Watabe, Y.; Kanazawa, K.; Fujita, T.; Ichikawa, J.
    Synthesis, 2017, 49, 3569-3575
  • "Lewis Acid-Promoted Single C-F Bond Activation of the CF3 Group: SN1'-type 3,3-Difluoroallylation of Arenes with 2-Trifluoromethyl-1-alkenes"
    Fuchibe, K.; Hatta, H.; Oh, K.; Oki, R.; Ichikawa, J.
    Angew. Chem. Int. Ed., 2017, 56, 5890–5893
  • "Brønsted Acid-catalyzed Tandem Cycloaromatization of Naphthalene-based Bisacetals: Selective Synthesis of ortho-Fused Six-hexagon Benzenoids"
    Takahashi, I.; Hayashi, M.; Fujita, T.; Ichikawa, J.
    Chem. Lett., 2017, 46(3), 392
  • "Domino C–F Bond Activation of CF3 Group: Synthesis of Fluorinated Dibenzo[a,c][7]annulenes from 2-Trifluoromethyl-1-alkenes and 2,2'-Diceriobiaryls"
    Fujita, T.; Takazawa, M.; Sugiyama, K.; Suzuki, N.; Ichikawa, J.
    Org. Lett., 2017, 19, 588
  • "Regioselective Synthesis of α-Fluorinated Cyclopentenones via Organocatalytic Difluorocyclopropanation and Fluorine-Directed and -Activated Nazarov Cyclization"
    Fuchibe, K.; Takayama, R.; Yokoyama, T.; Ichikawa, J.
    Chem. Eur. J., 2017, 23, 2831
  • "Facile Synthesis of Polycyclic Aromatic Hydrocarbons: Brønsted Acid-Catalyzed Dehydrative Cycloaromatization of Carbonyl Compounds in 1,1,1,3,3,3-Hexafluoropropan-2-ol"
    Fujita, T.; Takahashi, I.; Hayashi, M.; Wang, J.; Fuchibe, K.; Ichikawa, J.
    Eur. J. Org. Chem., 2017, 2, 262–265
  • "Preparation of 1,1-Difluoroallenes by Difluorovinylidenation of Carbonyl Compounds"
    Fuchibe, K.; Abe, M.; Oh, K.; Ichikawa, J.
    Org. Synth., 2016, 93, 352–366
  • "Aluminium-mediated Aromatic C–F Bond Activation: Regioswitchable Construction of Benzene-fused Triphenylene Frameworks"
    Suzuki, N.; Fujita, T.; Amsharov, K.; Ichikawa, J.
    Chem. Commun., 2016, 52, 12948–12951. [Cover Picture]
  • "Copper(I)-Catalyzed [4 + 1] Cycloaddition of Silyl Dienol Ethers with Sodium Bromodifluoroacetate: Access to β,β-Difluorocyclopentanone Derivatives"
    Fuchibe, K.; Aono, T.; Hu, J.; Ichikawa, J.
    Org. Lett., 2016, 18, 4502–4505
  • "Silver-Catalyzed Vinylic C–F Bond Activation: Synthesis of 2-Fluoroindoles from o-Sulfonamido-β,β-difluorostyrenes"
    Fujita, T.; Watabe, Y.; Yamashita, S.; Tanabe, H.; Nojima, T.; Ichikawa, J.
    Chem. Lett., 2016, 45, 964–966. [Editor’s Choice]
  • "Platform for Ring-Fluorinated Benzoheterole Derivatives: Palladium-Catalyzed Regioselective 1,1-Difluoroallylation and Heck Cyclization"
    Fujita, T.; Sugiyama, K.; Sanadas, S.; Ichitsuka, T.; Ichikawa, J.
    Org. Lett. , 2016, 18, 248-251
  • "Regioselective Synthesis of α,α-Difluorocyclopentanone Derivatives: Domino Nickel-Catalyzed Difluorocyclopropanation/Ring Expansion Sequence of Silyl Dienol Ethers"
    Aono, T.; Sasagawa, H.; Fuchibe, K.; Ichikawa, J.
    Org. Lett. , 2015, 17, 5736-5739
  • "Method for the Synthesis of Dibenzo[g,p]Chrysenes: Domino Friedel−Crafts-Type Cyclization of Difluoroethenes Bearing Two Biaryl Groups"
    Suzuki, N.; Fujita, T.; Ichikawa, J.
    Org. Lett., 2015, 17, 4984-4987
  • "Catalytic Defluorinative [3+2] Cycloaddition of Trifluoromethylalkenes with Alkynes via Reduction of Nickel(II) Fluoride Species"
    Fujita, T.; Arita, T.; Ichitsuka, T.; Ichikawa, J.
    Dalton Trans., 2015, 44, 19460-19463
  • "Pinpoint-Fluorinated Phenanthrene Synthesis Based on C–F Bond Activation of Difluoroalkenes"
    Fuchibe, K.; Morikawa, T.; Ueda, R.; Okauchi, T.; Ichikawa, J.
    J. Fluorine Chem. , 2015, 179, 106-115
  • "Nickel-Catalyzed Allylic C(sp3)–F Bond Activation of Trifluoromethyl Groups via β-Fluorine Elimination: Synthesis of Difluoro-1,4-dienes"
    5. Ichitsuka, T.; Fujita, T.; Ichikawa, J.
    ACS Catal. , 2015, 5, 5947-5950
  • "Ni-Catalyzed Synthesis of Fluoroarenes via [2+2+2] Cycloaddition Involving α-Fluorine Elimination"
    Fujita, T.; Watabe, Y.; Ichitsuka, T.; Ichikawa, J.
    Chem. Eur. J. , 2015, 21, 13225-13228
  • "Pinpoint-Fluorinated Phenacenses: New Synthesis and Solubility Enhancement Strategies"
    Fuchibe, K.; Morikawa, T.; Shigeno, K.; Fujita, T; Ichikawa, J.
    Org. Lett., 2015, 17, 1126-1129
  • "Organocatalytic, Difluorocarbene-Based S-Difluoromethylation of Thiocarbonyl Compounds"
    Fuchibe, K.; Bando, M.; Takayama, R.; Ichikawa, J.
    J. Fluorine Chem. , 2015, 171, 133-138
  • "A Versatile Difluorovinylation Method: Cross-Coupling Reactions of the 2,2-Difluorovinylzinc–TMEDA Complex with Alkenyl, Alkynyl, Allyl, and Benzyl Halides"
    Ichitsuka, T.; Takanohashi, T.; Fujita, T.; Ichikawa, J.
    J. Fluorine Chem., 2015, 170, 29-37

Review

  • 「Synthetic Methods for Ring-Fluorinated Pyrrole Derivatives」 Fujita, T.; *Ichikawa, J. , Heterocycles, 95, 694, 2017

Conference

  • The 3rd Symposium of Metal-Carbene Consortium
    "Transition Metal and Free Difluorocarbenes: Syntheses of Fluorinated Cyclopentanone Derivatives", Invited Lecture
    Ichikawa, J.
    2/5/2020~2/7/2020, San Antonio, USA
  • 4th International Synposium On Precisely Designed Catalysts with Customized Scaffolding
    "Synthesis of Difluoroalkenes and Fluorothiophenes via Difluorinated Thiiranes", Poster Presentation
    *Hachinohe, K.; Mukohara, I.; Yamada, A.; Matsumoto, K.; Fuchibe, K.; Ichikawa, J.
    12/3/2019~12/5/2019, 奈良, 日本
  • International Symposium on Fluorous Technologies 2019
    "Cyclizations in Cation-Stabilizing Hexafluoroisopropyl Alcohol (HFIP)", Invited Lecture
    Ichikawa, J.
    8/8/2019~8/11/2019, 上海, 中国
  • ACS Spring 2019 National Meeting & Expo
    "Difluoroallene chemistry: Versatile platform for syntheses of ring-fluorinated carbo- and heterocycles", Oral Presentation
    Ichikawa, J.
    3/31/2019~4/4/2019, Orland, U.S.A.
  • 24th Winter Fluorine Conference
    "Single C–F Bond Activation of the CF3 Group Using Lewis Acid Promotors", Oral Presentation
    Ichikawa, J.
    1/13/2019~1/18/2019, Florida, U.S.A.
  • The 22nd International Symposium on Fluorine Chemistry
    "Single C–F Bond Activation of the CF3 Group Using Lewis Acid Promotors", Oral Presentation
    Ichikawa, J.
    7/22/2018~7/27/2018, Oxford, U.K.
  • International Workshop on Bio-Driven Chemistry
    "Selective C–F Bond Activation of the CF3 Group Using Metal Promotors", Invited Lecture
    Ichikawa, J.
    7/18/2018~7/18/2018, Grenoble, France
  • International Colloquium Eolipila 2018
    "Controlled Generation of Metal and Free Difluorocarbenes And Its Synthetic Application", Invited Lecture
    Junji Ichikawa
    3/26/2018~3/26/2018, Lima, Peru
  • 10th Japanese-French Seminar on Fluorine
    "Regioselective CF2 Insertion with Metal and Free Difluorocarbenes: Syntheses of Fluorinated Cyclopentanone Derivatives", Oral Presentation
    Ichikawa, J.
    9/27/2017~9/29/2017, 金沢市, 日本
  • 精密制御反応場 第2回国際シンポジウム
    "Syntheses of Fluorinated Cyclopentanone Derivatives via Regioselective CF2 Insertion with Metal and Free Difluorocarbenes", Poster Presentation
    Ichikawa, J.
    5/12/2017~5/13/2017, 吹田市, 日本
  • The 253rd ACS National Meeting
    "Syntheses of fluorinated cyclopentanone derivatives via regioselective CF2 insertion with transition metal difluorocarbene complexes", Oral Presentation
    Ichikawa, J.
    4/2/2017~4/6/2017, San Francisco, USA
  • The 6th Korea-Japan-China Joint Seminar on Fluorine Chemistry
    "Regioselective CF2 Insertion by Transition metal Difluorocarbene complexes: Access to fluorinated cyclopentanones", Invited Lecture
    Ichikawa, J.
    9/7/2016~9/9/2016, Changwon, Korea
  • 9th French Japanese Seminar on Fluorine
    "Catalyst-Controlled Generation of Difluorocarbene and Its Synthetic Application", Invited Lecture
    Ichikawa, J.
    8/30/2015~9/1/2015, Nice, France
  • 21st International Symposium on Fluorine Chemistry & 6th International Symposium on Fluorous Technologies
    "Fluorinated Ring Constructions by Using Two Fluorines in a CF3 Group", Invited Lecture
    Ichikawa, J.
    8/23/2015~8/28/2015, Como, Italy
  • 43rd GRK 1582 (Fluorine as a Key Element) Kollegseminar
    "Metal-Catalyzed C–F Bond Activation Avoiding Oxidative Addition —Vinylic and Allylic C–F Bond Cleavage—", Invited Lecture
    Ichikawa, J.
    4/23/2015~4/23/2015, Berlin, Germany
  • 22nd Winter Flourine Conference
    "Metal-Catalyzed C–F Bond Activation Avoiding Oxidative Addition", Invited Lecture
    Ichikawa, J.
    1/11/2015~1/16/2015, St. Pete Beach, USA

National Conference

  • 日本化学会第100春季年会
    "金(I)触媒によるジフルオロアレンとスチレン類の[2+2]付加環化:ジフルオロメチレン置換シクロブタンの合成 ", 口頭発表
    *佐々木みぞれ、須藤恭介、不死原立樹、渕辺耕平、市川淳士
    3/22/2020~3/25/2020, 野田市
  • 日本化学会第100春季年会
    "金(I)触媒によるジフルオロアレンとニトリルオキシドの[2+3]付加環化:フッ素置換イソキサゾリンの合成", 口頭発表
    *佐近和樹、渕辺耕平、市川淳士
    3/22/2020~3/25/2020, 野田市
  • 日本化学会第100春季年会
    "3,3-ジフルオロペンタ-1,4-ジエンのC-F結合活性化を経るNa-zarov型環化:フッ素置換シクロペンタジエンの合成", 口頭発表
    *樋田源太郎、森岡龍太郎、藤田健志、市川淳士
    3/22/2020~3/25/2020, 野田市
  • 日本化学会第100春季年会
    "トリフルオロメチル基の選択的炭素−フッ素結合活性化を経るフッ素置換チオフェン誘導体の合成法", 口頭発表
    *不死原立樹、渕辺耕平、市川淳士
    3/22/2020~3/25/2020, 野田市
  • 日本化学会第100春季年会
    "銅(I)触媒によるアジドとジフルオロビニル亜鉛との脱フッ素[3+2]環化:フッ素置換トリアゾールの合成", 口頭発表
    *武石匡史、藤田健志、市川淳士
    3/22/2020~3/25/2020, 野田市
  • 日本化学会第100春季年会
    "Ni触媒を用いるスチレンとアラインの[4+2]付加環化反応:ジヒドロフェナントレンの合成", 口頭発表
    *久保輝彦、藤田健志、市川淳士
    3/22/2020~3/25/2020, 野田市
  • 日本化学会第100春季年会
    "ニッケル触媒を用いるトリフルオロメチルアルケンのC-F 結合活性化:インドールの位置選択的ジフルオロアリル化", 口頭発表
    *樋熊竜也、渡部陽太、井出啓介、藤田健志、市川淳士
    3/22/2020~3/25/2020, 野田市
  • 第42回フッ素化学討論会
    "ロジウム触媒によるビニル位炭素—フッ素/酸素結合の活性化:ビフェニレンとの[4+2]環化を経る置換フェナントレンの合成", 口頭発表
    *佐野公祐、渡部陽太、武石匡史、藤田健志、市川淳士
    11/21/2019~11/22/2019, 神戸
  • 第42回フッ素化学討論会
    "メチルアレーンを起点とするPAH合成:ジフルオロアルケンのドミノ環化を利用した手法", 口頭発表
    *高尾 豪、高橋洸樹、居島紫織、渕辺耕平、市川淳士
    11/21/2019~11/22/2019, 神戸
  • 第116回有機合成シンポジウム
    "トリフルオロメチル基の選択的炭素-フッ素結合活性化:1,1-ジフルオロアルケンの合成法", 口頭発表
    *渕辺耕平、八田 響、大木理江、不死原立樹、市川淳士
    10/31/2019~11/1/2019, 東京都
  • 第66回有機金属化学討論会
    "金(I)触媒による1,1-ジフルオロアレンとニトリルオキシドの[2+3]付加環化:環フッ素化イソキサゾリンの合成", ポスター発表
    *佐近和樹、渕辺耕平、市川淳士
    9/14/2019~9/16/2019, 八王子
  • 第66回有機金属化学討論会
    "ロジウム触媒によるビニル位炭素—フッ素/酸素結合の活性化:ビフェニレンとの[4+2]環化を経る置換フェナントレンの合成", 口頭発表
    *藤田健志、渡部陽太、佐野公祐、武石匡史、市川淳士
    9/14/2019~9/16/2019, 八王子
  • 有機合成化学協会東北支部 春の講演会
    "フッ素を電子供与基として活用する有機合成反応", 招待講演
    市川淳士
    6/15/2019~6/15/2019, 仙台
  • 第115回有機合成シンポジウム
    "酸を用いた芳香環炭素-フッ素結合活性化を経る多環式芳香族炭化水素の合成法", 口頭発表
    *藤田健志、鈴木直人、福田拓也、市川淳士
    6/3/2019~6/4/2019, 仙台
  • 第77回有機合成化学協会関東支部シンポジウム
    "ジフルオロメチルカチオンの連続環化による置換アセンの効率的合成法", 口頭発表
    *高尾 豪、筥崎智弘、渕辺耕平、市川淳士
    5/2019~5/2019, 横浜
  • 日本化学会第99春季年会
    "スルホンアミド置換スチレンの酸化的環化によるトリフルオロメチルインドールの合成法", 口頭発表
    *井出啓介、野島智也、藤田健志、市川淳士
    3/16/2019~3/19/2019, 神戸
  • 日本化学会第99春季年会
    "酸による芳香族炭素-フッ素結合活性化:フルオロベンゾフランとアレーンとのカップリング", 口頭発表
    *森岡龍太郎、福田拓也、藤田健志、市川淳士
    3/16/2019~3/19/2019, 神戸
  • 日本化学会第99春季年会
    "ブレンステッド酸触媒によるらせん状多環式芳香族炭化水素の合成", 口頭発表
    *庄司訓章、林 雅樹、藤田健志、市川淳士
    3/16/2019~3/19/2019, 神戸
  • 日本化学会第99春季年会
    "フルオロアルケンの求電子的環化によるピンポイントフッ素化ナフトチオフェンの合成", 口頭発表
    津田修成、渕辺耕平、市川淳士
    3/16/2019~3/19/2019, 神戸
  • 日本化学会第99春季年会
    "1,1-ジフルオロアレンとアルデヒドの[3+2]付加環化:フッ素置換ジヒドロフランの合成", 口頭発表
    *藤木裕介、佐近和樹、須藤恭介、市川淳士
    3/16/2019~3/19/2019, 神戸
  • 日本化学会第99春季年会
    "チイランの環拡大を経るチオフェン環構築法:チエノヘテロールの合成", 口頭発表
    *向原伊吹、八戸康成、山田淳史、渕辺耕平、市川淳士
    3/16/2019~3/19/2019, 神戸
  • 日本化学会第99春季年会
    "トリフルオロメチル基の選択的炭素-フッ素結合活性化を経る1,1-ジフルオロアルケンの合成法", 口頭発表
    *不死原立樹、大木理江、渕辺耕平、市川淳士
    3/16/2019~3/19/2019, 神戸
  • 第41回フッ素化学討論会
    "酸による芳香族炭素-フッ素結合活性化:多環式芳香族炭化水素の合成法", 口頭発表
    *藤田健志、福田拓也、鈴木直人、市川淳士
    10/25/2018~10/26/2018, 弘前
  • 第41回フッ素化学討論会
    "金(I)触媒を用いるジフルオロアレンの[2+3]および[3+2]付加環化:フッ素置換ヘテロ五員環化合物の合成", 口頭発表
    *佐近和樹、須藤恭介、藤木裕介、渕辺耕平、市川淳士
    10/25/2018~10/26/2018, 弘前
  • 第65回有機金属化学討論会
    "Gold-Catalyzed [2 + 3] and [3 + 2] Cycloadditions of Difluoroallenes", 口頭発表
    *Fuchibe, K.; Suto, K.; Sakon, K.; Ichikawa, J.
    9/19/2018~9/21/2018, 京都
  • 第113回有機合成化学シンポジウム
    "HFIP溶媒を用いたブレンステッド酸触媒による芳香環増環反応", 口頭発表
    *藤田健志、高橋一光、林雅樹、庄司訓章、市川淳士
    6/6/2018~6/7/2018, 名古屋
  • 新学術領域研究「精密制御反応場」第4回公開シンポジウム
    "フッ素脱離過程を活用する選択的sp3炭素−フッ素結合活性化", 口頭発表
    市川淳士
    5/10/2018~5/11/2018, 札幌
  • 第1回「フッ素と医療の研究最前線」
    "含フッ素小分子から生理活性物質の構成要素を作るーフッ素置換基の特性を活用してー", 招待講演
    市川淳士
    12/26/2017~12/26/2017, 桐生市

Award

  • 「有機合成化学協会賞」
    受賞者:市川淳士
    贈呈元:公益財団法人 有機合成化学協会
    受賞日:2/6/2019
  • 「日本化学会 学術賞」
    受賞者:市川淳士
    贈呈元:日本化学会
    受賞日:3/2015

Media

  • Synfacts, 雑誌記事
    Fujita, T.; Sugiyama, K.; Sanadas, S.; Ichitsuka, T.; Ichikawa, J., 1/2016
    PDF File
  • Synfacts, 雑誌記事
    Suzuki, N.; Fujita, T.; Ichikawa, J., 11/2015
    PDF File