Grant-in-Aid for Scientific Research on Innovative AreasPrecise Formation of a Catalyst Having a Specified Field for Use in Extremely Difficult Substrate Conversion Reactions

Tetsuya Satoh » Japanese

Affiliation Department of Chemistry, Graduate School of Science, Osaka City University
Position Professor
Contact Email
HP http://www.sci.osaka-cu.ac.jp/chem/orc/index_en.html
Speciality organometallic chemistry, synthetic organic chemistry
Keyword tranistion-metal catalyst, C–H bond cleavage, direct coupling
Institute The Chrmical Society of Japan, The Society of Synthetic Oranic Chemistry, Japan, The Kinki Chemical Society Japan

Abstract

Development of Molecular Transformation Involving Decarboxylation/Carboxylation on Porous Reaction Field

Achievement

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Original papers

  • "Cerium(IV) Carboxylate Photocatalyst for Catalytic Radical Formation from Carboxylic Acids: Decarboxylative Oxygenation of Aliphatic Carboxylic Acids and Lactonization of Aromatic Carboxylic Acids"
    Shirase, S.; Tamaki, S.; Shinohara, K.; Hirosawa, K.; *Tsurugi, H.; *Satoh, T.; *Mashima, K.
    J. Am. Chem. Soc. , 2020, 142(12), 5668-5675
  • "Rhodium(III)-catalyzed Redox-neutral Coupling of α-Trifluoromethylacrylic Acid with Benzamides through Directed C–H Bond Cleavage"
    Yoshimoto, R.; Usuki, Y.; *Satoh, T.
    Chem. Asian J., 2020, 15(6), 802-806
  • "Iridium(III)‐Catalyzed Dehydrogenative Coupling of Salicylic Acids with Alkynes: Synthesis of Highly Substituted 1‐Naphthol Derivatives"
    Hirosawa,K.; Usuki, Y.; *Satoh, T.
    Adv. Synth. Catal., 2019, 361(22), 5253-5257
  • "Theoretical Investigation of Regioselectivity in the Rh‐Catalyzed Coupling Reaction of 3‐Phenylthiophene with Styrene"
    Hayashi, Y; Satoh, T.; *Miura, M.; *Kawauchi, S.
    Eur. J. Org. Chem., 2019, (19), 2998-3004
  • "Rhodium(III)-Catalyzed β-Arylation and -Alkenylation of α-Trifluoromethylacrylic Acid"
    Yoshimoto, R.; Usuki, Y.; *Satoh, T.
    Chem. Lett. , 2019, 48(5), 461-464
  • "Total Syntheses and Configuration Assignments of JBIR-06 and Related Depsipeptides"
    Hamada, C.; *Usuki, Y.; Takeuchi, D.; Ogawa, H.; Abe, R.; Satoh, T.
    Org. Lett., 2019, 21(4), 965-968
  • "Rhodium(III)‐Catalyzed Direct Alkenylation of Benzothiophenes and Related Heterocycles with Alkynes"
    Morita, T.; Morisaka, H.; *Satoh, T.; *Miura, M.
    Asian J. Org. Chem., 2018, 7(7), 1330-1333
  • "Rhodium‐Catalyzed peri‐Selective Direct Alkenylation of 1‐(Methylthio)naphthalene"
    Shigeno, M.; Nishii, Y.; Satoh, T.; *Miura, M.
    Asian J. Org. Chem., 2018, 7(7), 1334-1337
  • "Iridium‐Catalyzed Aerobic Coupling of Salicylaldehydes with Alkynes: A Remarkable Switch of Oxacyclic Product"
    Yamane, S.; Hinoue, T.; Usuki, Y.; Itazaki, M.; Nakazawa, H.;Hayashi, Y.; Kawauchi, S.; *Miura, M.; *Satoh, T.
    Chem. Eur. J., 2018, 24(31), 7852-7855
  • "Rhodium(III)-Catalyzed Oxidative Coupling of N-Phenylindole-3-carboxylic Acids with Alkenes and Alkynes via C4-H and C2-H/C2'-H Bond Cleavage"
    Okada, T.; Sakai, A.; Hinoue, T.; *Satoh, T.; Hayashi, Y.; Kawauchi, S.; Chandrababunaidu, K.; *Miura, M.
    J. Org. Chem., 2018, 83(10), 5639-5649
  • "Synthesis of Enol Esters through Silver-catalyzed or -mediated Hydroacyloxylation of Internal Alkynes"
    Kikui, N.; Hinoue, T.; Usuki, Y.; *Satoh, T.
    Chem. Lett., 2018, 47(2), 141-143
  • "Rhodium(III)-Catalyzed Ortho-Alkenylation of Anilines Directed by a Removable Boc-Protecting Group"
    Morita, T.; Satoh, T.; Miura, M.
    Org. Lett., 2017, 19(7), 1800-1803
  • "Construction of Bisbenzofuro[2,3-b:3',2'-e]pyridines by Palladium-Catalyzed Double Intramolecular Oxidative C-H/C-H Coupling"
    Kaida, H.; Goya, T.; Nishii, Y.; Hirano, K.;. Satoh, T.; Miura, M.
    Org. Lett., 2017, 19(5), 1236-1239
  • "Synthesis of Difluorinated Enynes through Sonogashira-Type Coupling"
    Fujino, T.; Hinoue, T.; Usuki, Y.; Satoh, T.
    Org. Lett., 2016, 18(21), 5688-5691
  • "Ruthenium-Catalyzed Cross-Coupling of Maleimides with Alkenes"
    Morita, T.; Akita, M.; Satoh, T.; Kakiuchi, F.; Miura, M.
    Org. Lett., 2016, 18(18), 4598-4601
  • "Regioselective Synthesis of Benzophosphole Derivatives via Direct ortho-Alkenylation and Cyclization of Arylthiophosphinamides"
    Unoh, Y.; Yokoyama, Y.; Satoh, T.; Hirano, K.; Miura, M.
    Org. Lett., 2016, 18(20), 5436-5439

Books

  • 「Rhodium(III)-Catalyzed Annulative Carbon–Hydrogen Bond Functionalization」
    *Satoh, T.; *Miura, M.
    「Rhodium Catalysis in Organic Synthesis: Methods and Reactions」,Tanaka, K., Wiley-VCH, 2019, 489-519
  • 「Vinylation Using a Rhodium(III) Catalyst」
    Satoh, T.; Miura, M.
    「Science of Synthesis (Vol. Catalytic Transformations via C–H Activation 1)」,Yu, J.-Q., Georg Thieme, 2016, 197-228
  • 「Reactions Involving Elimination of CO2 and Ketones」
    Satoh, T.; Miura, M.
    「Cleavage of Carbon-Carbon Single Bonds by Transition Metals」,Murakami, M.; Chatani, N., Wiley-VCH, 2016, 119-163

Conference

  • 10th OCARINA International Symposium
    "Iridium-Catalyzed Dehydrogenative Coupling of Aromatic Carboxylic Acids with Internal Alkynes", Poster Presentation
    Hirosawa, K.; Usuki, Y.; Satoh, T.
    3/5/2019~3/6/2019, Osaka, Japan
  • 10th OCARINA International Symposium
    "Rhodium(III)-Catalyzed 1,4-Addition of Arylboronic Acids to alpha,beta-Unsaturated Carboxylic Acids", Poster Presentation
    Yoshimoto, R.; Usuki, Y.; Satoh, T.
    3/5/2019~3/6/2019, Osaka, Japan
  • The 4th International Symposium on C-H Activation (ISCHA4)
    "Regioselective C–H Functionalization under Rhodium(III)-Catalysis ", Invited Lecture
    Satoh, T.
    8/30/2018~9/2/2018, Yokohama, Japan
  • 9th OCARINA International Symposium
    "Synthesis of pai-Conjugated Molecules via Transition-Metal-Catalyzed C-H Functionalization", Invited Lecture
    Satoh, T.
    3/6/2018~3/7/2018, Osaka, Japan
  • International Symposium on Pure & Applied Chemistry 2017
    "Transition-Metal-Catalyzed Regioselective C-H Functionalization", Invited Lecture
    Satoh, T.
    6/8/2017~6/10/2017, Saigon, Vietnam
  • International Symposium on C–O Activation
    "Transition-Metal-Catalyzed Transformation of Benzoic Acids and Related Compounds", Invited Lecture
    Satoh, T.
    10/25/2016~10/27/2016, Himeji, Japan
  • 3rd International Conference on Organometallics and Catalysis
    "Rhodium(III)-Catalyzed Regioselective C–H Functionalization", Invited Lecture
    Satoh, T.
    8/28/2016~8/30/2016, Seoul, South Korea

Award

  • 「大阪市立大学教員活動表彰 研究分野」
    受賞者:佐藤哲也
    贈呈元:大阪市立大学
    受賞日:5/10/2017